CAS number：4488-22-6 molecular formula：C20H16N2
Application Novel axially chiral Rh N-heterocyclic carbene complexes were prepared from axially dissymmetric 1,1'-binaphthalenyl-2,2'-diamine and applied in the Rh-catalyzed enantioselective hydrosilylation of methyl ketones. The enantioselective direct aldol reaction, organocatalyzed by recoverable BINAM- prolinamide derivatives can be highly accelerated by a catalytic amount of a carboxylic acid without a detrimental of the obtained enantioselectivities.
| Chinese alias | ( )-1,1'-双(2-萘胺) | 1,1'-联萘-2,2'-二胺 | 2,2'-二氨基-1,1'-联萘 | ||
| English alias | N-Hexadecanoyl-Serinemonosodiumsalt | WLN: L66J CZ B- 2 | (r)-binaphthyldiamine | (S)-(-)-1,1'-Binaphthalene-2,2'-diamine | 2,2'-diamino-1,1'-binaphthalene | FT-0637744 | (+)-2,2'-Diamino-1,1'-binaphthyl | (S)-2,2'-Diamino-1,1'-binaphthyl | 1-(2-aminonaph | ||
| CAS number | 4488-22-6 | molecular formula | C20H16N2 |
| molecular weight | 284.35 g/mol | Exact mass | ≥97% |
| PSA | 52.000 Ų | logp | 4.700 |
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