用途: 催化配体用于: 氰丙烯环立体选择性合成氰基取代二氢吡咯 通过动力学拆分,铑催化炔烃的分子间对映选择性氢酰化,生成 α-和 β-取代的不饱和酮 立体选择性合成 β-环糊精-铑催化的氨基丙烯腈的不对称加氢反应 铑催化的 β-不对称氢化合成反-1,3-氨基醇-酮酰胺中间体 铑催化不对称氢化乙酰氨基茚立体选择性合成乙酰氨基茚 说明: (1R,1'R,2S,2' S )-DuanPhos 是转换富电子的手性膦配体,主要用于过渡金属催化的不对称氢化反应。
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(1R,1'R,2S,2'S)-(+)-2,2'-Di-t-butyl-2,3,2',3'-tetrahydro-1,1'-bi-1H-isophosphindole
Dangerous GoodsCAS number:528814-26-8 molecular formula:C24H32P2
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Specs
| Chinese alias | - | ||
| English alias | AKOS025295428 | RcSp-DuanPhos | (1R,1'R,2S,2'S)-DuanPhos | DTXSID10662330 | MFCD07781993 | (1R)-2-tert-butyl-1-[(1R)-2-tert-butyl-1,3-dihydroisophosphindol-1-yl]-1,3-dihydroisophosphindole | (1R,1'R,2S,2'S)-(+)-2,2'-Di-t-butyl-2,3,2',3'-tetrahydro-1,1'-bi | ||
| CAS number | 528814-26-8 | molecular formula | C24H32P2 |
| molecular weight | 382.46 g/mol | Exact mass | - |
| PSA | 0.000 Ų | logp | 3.800 |
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3
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528814-26-8 | (1r,1′r,2s,2′s)-duanphos.pdf





