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(R)-(–)-VAPOL hydrogenphosphate

Dangerous Goods

CAS number:871130-18-6    molecular formula:C40H25O4P

overview

compound introduction

用途: 磺胺加成到 Boc-活化芳基亚胺反应中的手性布朗斯特酸催化剂。 Application: Catalyst involved in: Desymmetrization of meso-aziridines Asymmetric aza-Darzens aziridine synthesis Enantioselective ring-opening of mono-and bicyclic N-acyl meso aziridines Condensation of aldehydes with amino benzenesulfonamides Pictet-Spengler reactions

Specs

Chinese alias(R)-2,2'-二苯基-3,3'-联菲-4,4'-二基磷酸酯 | (R)-VAPOL 磷酸 | 18-羟基-8,9-二苯基-联菲并[4,3-d:3',4'-f][1,3,2]二噁磷杂庚英-18-氧化物 | (8aR)-18-羟基-8,9-二苯基-18-氧化物-二苯并菲[4,3-d:3'',4''-f] [1,3,2]二氧杂磷醚
English alias(8aR)-18-Hydroxy-8,9-diphenyl-18-oxide-diphenanthro[4,3-d:3'',4''-f][1,3,2]dioxaphosphepin | (R)-2,2′-Diphenyl-3,3′-biphenanthryl-4,4′-diyl phosphate | (R)-VAPOL phosphoric acid | 18-Hydroxy-8,9-diphenyl-diphenanthro[4,3-d:3′,4′-f][1,3,2]dioxaphosphepin-1
CAS number871130-18-6molecular formulaC40H25O4P
molecular weight600.6 g/molExact mass≥98%,≥99%(ee)
PSA55.800 Ųlogp10.600

numbering system

No numbering system information yet

physicochemical properties

No physical and chemical property information yet

Safety information

Signal word:
Warning
Hazard Statement:
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H302: 吞食有害
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染:用水充分清洗。 P301+P312: 如误吞咽:如感觉不适,呼叫急救中心/医生。
WGK Germany:
3

Production methods and uses

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Related

upstream information

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downstream information

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MSDS

Found 1 shareMSDS
871130-18-6 | (R)-(–)-VAPOL hydrogenphosphate.pdf