应用 [1,3-双(二苯基膦基)丙烷]三氟甲磺酸钯(II)可作为催化剂,用于通过2-卤代-N-Ms 芳胺和苄基卤化物/磺酸盐的亲核取代,以及 CH 官能化和芳构化反应,合成菲啶。 Description [1,3-Bis(diphenylphosphino)propane]palladium(II) triflate can be used as a catalyst to synthesize phenanthridines by the reaction between 2-halogeno-N-Ms arylamines and benzyl halides/sulfonates via nucleophilic substitution followed by C-H functionalization and aromatization reaction.
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[1,3-Bis(diphenylphosphino)propane]palladium(II) triflate
Dangerous GoodsCAS number:137846-38-9 molecular formula:C29H26F6O6P2PdS2
overview
compound introduction
Specs
| Chinese alias | - | ||
| English alias | 3-Diphenylphosphanylpropyl(diphenyl)phosphane;palladium(2+);trifluoromethanesulfonate | [1,3-Bis(diphenylphosphino)propane]palladium(II) triflate | Pd(OTf)2(dippp) | ||
| CAS number | 137846-38-9 | molecular formula | C29H26F6O6P2PdS2 |
| molecular weight | 817 g/mol | Exact mass | - |
| PSA | - | logp | - |
numbering system
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physicochemical properties
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Safety information
pictogram:
GHS07
Signal word:
Warning
Hazard Statement:
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H302: 吞食有害 H312: 皮肤接触有害 H332: 吸入有害 H302+H312+H332: 吞咽,皮肤接触或吸入有害。
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染:用水充分清洗。 P321: 特殊处理(请参阅此标签上的...)。 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P270: 使用本产品时,请勿进食、饮水或吸烟。 P304+P
WGK Germany:
3
Production methods and uses
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Related
upstream information
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downstream information
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MSDS
Found 1 shareMSDS
137846-38-9 | [1,3-Bis(diphenylphosphino)propane]palladium(II)triflate.pdf





