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Aluminum trifluoromethanesulfonate

Dangerous Goods

CAS number:74974-61-1    molecular formula:C3AlF9O9S3

overview

compound introduction

应用: 三氟甲磺酸铝 (三氟磺酸铝或Al(OTf)3) 可用作以下反应的催化剂: 通过不饱和醇的环化异构化进行环醚的区域选择性合成。 糖类转化为5-羟甲基糠醛 (5-HMF)。 与Pd(OAc)2/BINAP 一起参与苯乙炔的甲氧羰基化反应。 Aluminum trifluoromethanesulfonate (aluminum triflate or Al(OTf)3) can be employed as a catalyst: • In the regioselective synthesis of cyclic ethers by cycloisomerization of unsaturated alcohols In the conversion of saccharides into 5-hydroxymethylfurfural (5-HMF). • Along with Pd(OAc)2/BINAP for the methoxycarbonylation reaction of phenylacetylene.

Specs

Chinese alias三(三氟甲烷)铝 | 三(三氟甲磺酸铝)铝 | 三氟甲磺酸铝
English aliasAluminum triflate | Aluminum tris(trifluoromethanesulfonate) | Tris(trifluoromethanesulfonato)aluminum
CAS number74974-61-1molecular formulaC3AlF9O9S3
molecular weight474.19 g/molExact mass≥98%
PSA197.000 Ųlogp-

numbering system

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physicochemical properties

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Safety information

pictogram:
GHS05
Signal word:
Danger
Hazard Statement:
H314: 造成严重的皮肤灼伤和眼睛损伤
Statement of Preventive Measures:
P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P301+P330+P331: 如误吞咽:漱口。不要诱导呕吐。 P304+P340: 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。 P363: 再次使用之前,请清洗受污染的衣物。 P305+P354+P338: 如果进入眼睛:立即用水冲洗几分钟

Production methods and uses

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upstream information

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downstream information

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MSDS

Found 1 shareMSDS
74974-61-1 | Aluminum trifluoromethanesulfonate.pdf