All
Chemical Reagents
Biomedicine
Organic raw materials
Inorganic chemical industry
intermediate
Agricultural chemicals
Auxiliaries and catalysts
Fragrances and Flavors
Dyes and Pigments
Daily chemical industry

Methyl 2-bromoacrylate

Dangerous Goods

CAS number:4519-46-4    molecular formula:C4H5BrO2

overview

compound introduction

Product Application: Methyl α-bromoacrylate can undergo radical copolymerization with vinyl triacetoxysilane (VTAS) in the presence of azobisisobutyronitrile as the initiator. Dibromocyclopropanation of methyl α-bromoacrylate can yield methyl 1,1,2-tribromocyclopropanecarboxylate. It may be reduced with zinc dust and deuterium oxide to synthesize. Methyl acrylate-α-d with a high isotopic purity. These may undergo conjugate addition with methoxide, thiolates, oxime anions, hydrazones and EtZnCl to afford ester enolates.

Specs

Chinese alias-
English aliasSCHEMBL600306 | Methyl alpha-bromoacrylate, 95% | AKOS015950954 | FT-0766267 | Methyl alpha -bromoacrylate | NSC24144 | NSC-24144 | Methyl alpha-bromoacrylate | MFCD08276754 | InChI=1/C4H5BrO2/c1-3(5)4(6)7-2/h1H2,2H | DTXSID00282086 | EN300-77113 | A-brom
CAS number4519-46-4molecular formulaC4H5BrO2
molecular weight164.99 g/molExact mass≥96%
PSA26.300 Ųlogp1.600

numbering system

No numbering system information yet

physicochemical properties

No physical and chemical property information yet

Safety information

pictogram:
GHS07 , GHS02
Signal word:
Warning
Hazard Statement:
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H226: 易燃液体和蒸气
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370+P378: 火灾时:使用干砂、干粉或抗醇泡沫灭火。 P210: 远离热源,热表面,火花,明火和其他点火源。 - 禁止抽烟。 P302+P352: 如皮肤沾染:用水充分清洗。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/
WGK Germany:
3
Personal protective equipment:
Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Production methods and uses

No production method and use information yet

Related

upstream information

No upstream information yet

downstream information

No downstream information yet

MSDS

Found 1 shareMSDS
4519-46-4 | Methyl α-bromoacrylate.pdf