compound introduction
应用： AlPhos是一种双芳基单膦配体，可用于： ①Pd催化的Buchwald-Hartwig交叉偶联反应； ②Pd催化各种活化芳基、杂芳基三氟甲磺酸酯和溴化物成为高区域选择性芳基氟化物的氟化反应； ③在钯催化剂存在下，通过硫醇和芳香亲电物质的C–S交叉偶联反应制备芳基硫醚。
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AlPhos
Dangerous GoodsCAS number：1805783-60-1 molecular formula：C52H67F4OP
overview
Specs
| Chinese alias | 二-1-金刚烷基(4″-丁基-2″,3″,5″,6″-四氟-2',4',6'-三异丙基-2-甲氧基-间三联苯)膦 | [4''-丁基-2'',3'',5'',6''-四氟-3-甲氧基-2',4',6'-三异丙基[1,1':3',1''-三联苯]-2-基]二(金刚烷-1-基)膦 | 磷酸铝 | ||
| English alias | Di-1-adamantyl(4″-butyl-2″,3″,5″,6″-tetrafluoro-2′,4′,6′-triisopropyl-2-methoxy-meta-terphenyl)phosphine | [4''-Butyl-2'',3'',5'',6''-tetrafluoro-3-methoxy-2',4',6'-tris(1-methylethyl)[1,1':3',1''-terphenyl]-2-yl]bis(tricyclo[3.3.1.1(3,7)]dec-1-yl)phosphi | ||
| CAS number | 1805783-60-1 | molecular formula | C52H67F4OP |
| molecular weight | 815.06 g/mol | Exact mass | ≥98% |
| PSA | 9.200 Ų | logp | 15.700 |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
Signal word：
Warning
Hazard Statement：
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H302: 吞食有害
Statement of Preventive Measures：
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。
Production methods and uses
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Related
upstream information
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downstream information
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MSDS
Found 1 shareMSDS
1805783-60-1 | AlPhos.pdf
