2-Allylcyclohexanone is a β,γ-unsaturated ketone. Selective oxidation of 2-allylcyclohexanone by benzonitrile-hydrogen peroxide has been reported. Asymmetric synthesis of 2-alkylcyclohexanones by alkylation of cyclohexanone enamines (III) of L-proline ester derivatives has been described. Oxidation of 2-allylcyclohexanone by 90% hydrogen peroxide catalyzed by arsonated polystyrene has been studied.2-Allylcyclohexanone may be used in the synthesis of the following: · bicyclo[3.3.1]non-2-en-9-one · R-(-)-epilachnene, an antipode of the defensive droplets from the Mexican bean beetle, Epilachna varivestis 2-Allylcyclohexanone is a β,γ-unsaturated ketone. Selective oxidation of 2-allylcyclohexanone by benzonitrile-hydrogen peroxide has been reported. Asymmetric synthesis of 2-alkylcyclohexanones by alkylation of cyclohexanone enamines (III) of L-proline ester derivatives has been described. Oxidation of 2-allylcyclohexanone by 90% hydrogen peroxide catalyzed by arsonated polystyrene has been studied.
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2-Allylcyclohexanone
Dangerous GoodsCAS number:94-66-6 molecular formula:C9H14O
overview
compound introduction
Specs
| Chinese alias | 2-烯丙基环己-1-酮 | ||
| English alias | SY052152 | 2-Allylcyclohexanone | 2-allyl-cyclohexanone | 2-Allylcyclohexanone, 97% | EINECS 202-352-2 | 2-Allylcyclohexanone, >/=97% | Cyclohexanone, 2-(2-propenyl)- | DTXSID90883283 | AS-35729 | 02QB6788GC | Cyclohexanone, 2-(2-propen-1-yl)- | AI3-07009 | ||
| CAS number | 94-66-6 | molecular formula | C9H14O |
| molecular weight | 138.21 g/mol | Exact mass | Reagent Grade |
| PSA | 17.100 Ų | logp | 2.100 |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram:
GHS07
Signal word:
Warning
Hazard Statement:
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H302: 吞食有害 H312: 皮肤接触有害 H332: 吸入有害
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染:用水充分清洗。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P270: 使用本产品时,请勿进食、饮水
WGK Germany:
3
Personal protective equipment:
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Production methods and uses
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Related
upstream information
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downstream information
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MSDS
Found 1 shareMSDS
94-66-6 | 2-Allylcyclohexanone.pdf





