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(4R,4''R,5S,5''S)-2,2''-(1-Methylethylidene)bis[4,5-dihydro-4,5-diphenyloxazole]

CAS number:157904-67-1    molecular formula:C33H30N2O2

overview

compound introduction

(4R,4′R,5S,5′S)-2,2′-(1-Methylethylidene) or (4S,5R)-Bis-Phbox) can be used as a ligand: To prepare selective exo-catalysts for enantioselective 1,3-dipolar cycloaddition reactions. In the asymmetric aminooxygenation of alkenes in the presence of tetramethylaminopyridyl radical (TEMPO) as an oxidant and copper(II) triflate as a catalyst. In asymmetric aminofluorination of olefins using an iron catalyst. (4R,4′R,5S,5′S)-2,2′-(1-Methylethylidene) or (4S,5R)-Bis-Phbox) can be used as a ligand: To prepare selective exo-catalysts for enantioselective 1,3-dipolar cycloaddition reactions. In the asymmetric aminooxygenation of alkenes in the presence of tetramethylaminopyridyl radical (TEMPO) as an oxidant and copper(II) triflate as a catalyst. In asymmetric aminofluorination of olefins using an iron catalyst.

Specs

Chinese alias(4R,4'R,5S,5'S)-2,2'-异丙叉双[4,5-二氢-4,5-二苯基恶唑]
English alias(4R,5S)-2-[2-[(4R,5S)-4,5-diphenyl-4,5-dihydro-1,3-oxazol-2-yl]propan-2-yl]-4,5-diphenyl-4,5-dihydro-1,3-oxazole | AS-73863 | D72018 | (4R,4'R,5S,5'S)-2,2'-(1-Methylethylidene)bis[4,5-dihydro-4,5-diphenyloxazole] | AKOS037647498 | (4R,4'R,5S,5'S)-2,2'-(1-
CAS number157904-67-1molecular formulaC33H30N2O2
molecular weight486.6 g/molExact mass≥98%,≥99%(ee)
PSA43.200 Ųlogp6.900

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MSDS

Found 1 shareMSDS
157904-67-1 | 2,2-Bis[2-(4R,5S-diphenyl-1,3-oxazolinyl)]propane.pdf