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Phenylboronic acid (PBA)(contains varying amounts of Anhydride)

Dangerous Goods

CAS number:98-80-6    molecular formula:C6H7BO2

overview

compound introduction

溶于甲醇和乙醇,难溶于水和乙醚。 溶解度分别为:10 g/L水 (20°C),溶于 1.75%苯 、1.2 %二甲苯、 178 %甲醇和30.2%乙醚 Phenylboronic acid may be employed in the following reactions: Rhodium-catalyzed intramolecular amination. Pd-catalyzed direct arylation. Mizoroki-Heck and Suzuki-Miyaura coupling reactions catalyzed by palladium nanoparticles. Palladium-catalyzed stereoselective Heck-type reaction. Highly effective Palladium-catalyzed arylation Suzuki-Miyaura cross-coupling in water. Phenylboronic acid may be employed as reagent in the preparation of: Ni(II) pincer complex and Pd(II) pyridoxal hydrazone metallacycles as catalysts for the Suzuki-Miyaura cross-coupling reactions. N-type polymers for all-polymer solar cells. Novel series of potent and selective mTOR kinase inhibitors. Inhibitors of lactate dehydrogenase against cancer cell proliferation. Contains varying amounts of phenylboronic anhydride.Microwave-assisted Suzuki coupling of aryl chlorides with phenylboronic acid in the presence of Pd/C (catalyst) and water (solvent) has been described.Palladium-catalyzed cross-coupling reaction of phenylboronicacid with haloarenes to afford biaryls has been reported. Phenylboronic acid may be employed in the following reactions: Rhodium-catalyzed intramolecular amination. Pd-catalyzed direct arylation. Mizoroki-Heck and Suzuki-Miyaura coupling reactions catalyzed by palladium nanoparticles. Palladium-catalyzed stereoselective Heck-type reaction. Highly effective Palladium-catalyzed arylation Suzuki-Miyaura cross-coupling in water. Phenylboronic acid may be employed as reagent in the preparation of: Ni(II) pincer complex and Pd(II) pyridoxal hydrazone metallacycles as catalysts for the Suzuki-Miyaura cross-coupling reactions. N-type polymers for all-polymer solar cells. Novel series of potent and selective mTOR kinase inhibitors. Inhibitors of lactate dehydrogenase against cancer cell proliferation.

Specs

Chinese alias二羟基苯硼烷 | 苯基硼酸
English aliasPhenyldihydroxyborane | Borophenylic acid | Dihydroxy(phenyl)borane | Phenylboronic acid | Benzeneboronic acid | Dihydroxyphenylborane | USAF BO-2 | NSC 66487
CAS number98-80-6molecular formulaC6H7BO2
molecular weight121.93 g/molExact mass≥97%
PSA40.500 Ųlogp-

numbering system

No numbering system information yet

physicochemical properties

No physical and chemical property information yet

Safety information

pictogram:
GHS07
Signal word:
Warning
Hazard Statement:
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H302: 吞食有害
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染:用水充分清洗。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P270: 使用本产品时,请勿进食、饮水
WGK Germany:
3
Personal protective equipment:
dust mask type N95 (US),Eyeshields,Gloves
RTECS:
CY8575000

Production methods and uses

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Related

upstream information

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downstream information

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MSDS

Found 1 shareMSDS
98-80-6 | Phenylboronic acid.pdf