定期/蒸馏前检测过氧化物的生成 应用 2,2,6,6-四甲基哌啶基氯化镁氯化锂复合物是非亲核性Knochel-Hauser碱, 主要用于官能化芳烃和杂芳烃的氧化,以制备相应的格氏试剂。它还可以用作通过催化剂转移缩聚合成Π-共轭聚合物过程的碱。使用Knochel-Hauser碱的选择性去质子化['使用Knochel-Hauser碱的选择性去质子化 Description 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex is a non-nucleophilic Knochel-Hauser base mainly used for the magnesiation of functionalized arenes and heteroarenes to prepare the corresponding Grignard reagents. It can also be used as a base in the synthesis of Π-conjugated polymers via catalyst-transfer polycondensation.Selective Deprotonations using Knochel-Hauser-Base
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2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution
CAS number:898838-07-8 molecular formula:C9H18Cl2LiMgN
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| Chinese alias | - | ||
| English alias | DTXSID30635642 | 2,2,6,6-tetramethylpiperidinylmagnesium chloride lithium chloride | lithium magnesium 2,2,6,6-tetramethylpiperidin-1-ide dichloride | JHBZAAACZVPPRQ-UHFFFAOYSA-L | TMPMgCl·LiCl | ||
| CAS number | 898838-07-8 | molecular formula | C9H18Cl2LiMgN |
| molecular weight | 242.40 g/mol | Exact mass | 1.0M in THF |
| PSA | - | logp | - |
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