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Krische Ir Catalyst: (S)-SEGPHOS, 3-nitrobenzoate ligated

CAS number:MFCD27978282    molecular formula:

overview

compound introduction

Description Catalyst developed by the Krische Group to affect the asymmetric carbonyl tert-prenylation (and allylation) from the alcohol or aldehyde oxidation level. Critical to the Krische group′s approach to Bryostatin 7, this catalyst is highly relevant for polyketide synthesis.Total Synthesis of Bryostatin 7 via C–C Bond-Forming Hydrogenation Description Catalyst developed by the Krische Group to affect the asymmetric carbonyl tert-prenylation (and allylation) from the alcohol or aldehyde oxidation level. Critical to the Krische group′s approach to Bryostatin 7, this catalyst is highly relevant for polyketide synthesis.Total Synthesis of Bryostatin 7 via C–C Bond-Forming Hydrogenation

Specs

Chinese alias-
English alias[(S)-(-)-5,5′-Bis(diphenylphosphino)-4,4′-bi-1,3-benzodioxole][3-nitrobenzenecarboxylato][1,2,3-η-2-propenyl]iridium(III)
CAS numberMFCD27978282molecular formula
molecular weight-Exact massReagent Grade
PSA-logp-

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