有醚样气味。能与水、醇类、醚类、酮类、酯类和烃类混溶。易燃。有刺激性。 氨基酸和肽的纸层析。溶剂。有机合成。高效液相色谱,紫外发光光度分析。 四氢呋喃(THF)是一种饱和环醚，主要用作有机溶剂。长期储存时，它会形成有机过氧化物。可通过添加丁基羟基甲苯(BHT)作为稳定剂而抑制这一过程。BHT能去除形成过氧化物所需的自由基。它是各种天然产物（聚醚类抗生素）的关键片段。THF可与硫化氢形成双水合物，其晶体结构已经过三维单晶研究法进行过研究。 应用： 干燥四氢呋喃(THF)已用于合成二氯{双[1,1′，1′′-(膦三基)三哌啶]钯[(P(NC5H10)3)2Pd(Cl)2]，广泛用作Heck反应中的催化剂。它已被用于各种芳基溴和烯烃的Heck交叉偶联反应介质。 Tetrahydrofuran (THF) is a saturated cyclic ether that is mainly used as an organic solvent. When stored for a long time, it forms organic peroxides. This process can be inhibited by adding butylhydroxytoluene (BHT) as a stabilizer. BHT removes free radicals needed to form peroxides. It is a key fragment of various natural products (polyether antibiotics). THF can form double hydrates with hydrogen sulfide, and its crystal structure has been studied by three-dimensional single crystal method. Application： Dried tetrahydrofuran (THF) has been used to synthesize dichloride {bis [1,1 ',1 "-(phosphine triyl) tripiperidine] palladium [(P(NC5H10)3)2Pd(Cl)2], which is widely used as a catalyst in Heck reactions. It has been used as a Heck cross-coupling reaction medium for various aryl bromine and olefin.
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Tetrahydrofuran(THF)
Dangerous GoodsCAS number：109-99-9 molecular formula：C4H8O
overview
compound introduction
Specs
| Chinese alias | 1,4-环氧丁烷 | 丁烯氧化物 | 四亚甲基氧化物 | 氧杂环戊烷 | ||
| English alias | THF | FT-0696552 | terahydrofuran | TETRAHYDROFURAN [IARC] | tetrahydrof uran | DTXCID501328 | EN300-21322 | Oxacyclopentane | Tetrahydrofuran, ACS reagent | tetrahyrdofuran | MFCD00005356 | terahyrofuran | AKOS000119982 | Dynasolve 150 | RCRA waste numbe | ||
| CAS number | 109-99-9 | molecular formula | C4H8O |
| molecular weight | 72.11 g/mol | Exact mass | 无水级 |
| PSA | 9.200 Ų | logp | 0.500 |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram：
GHS08 , GHS07 , GHS02
Signal word：
Danger
Hazard Statement：
H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H351: 怀疑引起遗传缺陷 H225: 高度易燃的液体和蒸气
Statement of Preventive Measures：
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P210: 远离热源，热表面，火花，明火和其他点火源。 - 禁止抽烟。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P233: 保持容器密闭。 P240: 地面/粘结容器和接收设备 P403+P23
WGK Germany：
1
Personal protective equipment：
Eyeshields,Faceshields,full-face respirator (US),Gloves,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter
RTECS：
LU5950000
UN Number：
2056
General hazardous chemicals：
一般危化品
Packing Group：
II
Production methods and uses
No production method and use information yet
Related
upstream information
No upstream information yet
downstream information
No downstream information yet
MSDS
Found 1 shareMSDS
109-99-9 | tetrahydrofuran | tetrahydrofuran | diethylene oxide
