通过在 THF 中用 SmI（2）还原偶氮苯来制备氢化偶氮苯。 氢化偶氮苯是氧化偶氮苯氢化成苯胺的中间体。 应用 作为以下反应的反应物： 与有机金属钽配合物发生的插入反应 三氯化钛（III）催化的还原反应，生成胺 研究苯重排的机理 与 N -杂环稳定的甲硅烷基发生的反应 二锰酰胺酰肼簇合物的合成 铁介导的肼还原反应，生成亚芳基铁立方烷 其他说明 含有不定量的偶氮苯 Hydrazobenzene has been prepared by the reduction of azobenzene by SmI(2) in THF. Hydrazobenzene is an intermediate in the hydrogenation of azoxybenzene to aniline. Application Reactant involved in: Insertion reactions with organometallic tantalum complexes Reduction reactions catalyzed by titanium(III) trichloride yielding amines Studying the mechanism of hydrazobenzene rearrangement Reaction with N -heterocyclic stable silylene Synthesis of dimanganese amide hydrazide cluster complexes Iron-mediated hydrazine reductions yielding iron arylimide cubanes Other Notes Contains varying amounts of azobenzene
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Hydrazobenzene
Dangerous GoodsCAS number：122-66-7 molecular formula：C12H12N2
overview
compound introduction
Specs
| Chinese alias | 二苯肼 | 1,2-二苯基肼 | ||
| English alias | (sym)-Diphenylhydrazine | N,N'-Bianiline | 1,2-diphenyldiazane | Hydrazobenzene | 1,2-DIPHENYLHYDRAZINE | Hydrazobenzen | N,N'-Diphenylhydrazine | ||
| CAS number | 122-66-7 | molecular formula | C12H12N2 |
| molecular weight | 184.24 g/mol | Exact mass | ≥95% |
| PSA | 24.100 Ų | logp | 2.900 |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram：
GHS08 , GHS09 , GHS07
Signal word：
Danger
Hazard Statement：
H302: 吞食有害 H410: 对水生生物有剧毒并具有长期持续影响 H350: 可能导致癌症
Statement of Preventive Measures：
P273: 避免释放到环境中。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P201: 使用前获取特殊说明 P308+P313: 如接触到或有疑虑：求医/就诊。 P270: 使用本产品时，请勿进食、饮水或吸烟。 P391: 收集溢出物 P410: 防止阳光直射 P202: 在阅读并理解所有安全预防措施之前，不要进行操作。 P330: 漱口 P301+P312: 如误吞咽：如感觉不适，呼叫急救中心/
WGK Germany：
3
Personal protective equipment：
dust mask type N95 (US), Eyeshields, Gloves, type P2 (EN 143) respirator cartridges
UN Number：
2811
General hazardous chemicals：
一般危化品
Packing Group：
Ⅰ
Production methods and uses
No production method and use information yet
Related
upstream information
No upstream information yet
downstream information
No downstream information yet
MSDS
Found 1 shareMSDS
122-66-7|1,2-二苯肼|1,2-diphenylhydrazine|sym-diphenyl hydrazine|hydrazobenzene
