( S,S )-(+)- N,N′-双（3,5-二- 叔 -丁基水杨醛）-1,2-环己烷二氨基锰 (III) 氯化物是一种能催化多种不对称转化的金属salen络合物。 产品应用： 反应物涉及： ct-DNA嵌入结合及自由基清除抗氧化活性的研究 苯氧基改性聚苯乙烯苯基乙烯基膦酸锆的固定化 用于研究对映选择性反应构象模型的衍生物的合成 催化剂涉及： 烯烃的不对称环氧化； 离子液体修饰介孔二氧化硅固定化用于外消旋仲醇的氧化动力学拆分； 二胺改性苯乙烯基膦酸氢锆固定化苯乙烯环氧化反应。 非官能化烯烃类的 Salen (Mn)-催化不对称环氧化反应。获得各种底物（特别是顺式-烯烃）的高对映立体选择性和产量。一些用途包括合成紫杉醇侧链和顺式-1-氨基-2-茚醇。Jacobsen 催化剂还用于硅烯醇醚的不对称 α-羟基化。用于各种烯烃不对称环氧化反应的催化剂。 Product Describtion: (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride is a metal-salen complex that can catalyze a variety of asymmetric transformations. Product Application: Reactant involved in: Studies of intercalative binding with ct-DNA and radical scavenging antioxidant activity Immobilization on phenoxy-modified zirconium poly(styrenephenylvinylphosphonate) Synthesis of derivatvies for studies of conformational models of enantioselective reactions Catalyst involved in: Asymmetric epoxidation of olefins Immobilization on ionic liquid modified mesoporous silica for oxidative kinetic resolution of racemic secondary alcohols Immobilization on diamine modified zirconium olig-styrenyl phosphonate hydrogen phosphate for epoxidation of styrene Salen (Mn)-catalyzed asymmetric epoxidation of unfunctionalized olefins. High enantioselectivities and yields are obtained for a variety of substrates, especially cis-alkenes. A few applications include the synthesis of the taxol side chain and cis-1-amino-2-indanol. Jacobsen′s catalyst has also been used in the asymmetric α-hydroxylation of silyl enol ethers.Catalyst for the enantioselective epoxidation of a variety of olefins.
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(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride
Dangerous GoodsCAS number：135620-04-1 molecular formula：[[[(CH3)3C]2C6H2-2-(O-)CH=N]2C6H10]MnCl
overview
compound introduction
Specs
| Chinese alias | (S,S)-雅可布逊催化剂 | (1S,2S)-(+)-[1,2-环己烷二胺氮-N,N'-双(3,5-二-叔丁基亚水杨基)]氯化锰(III) | (S,S)-雅可布逊催化剂氯化锰络合物 | ||
| English alias | MFCD02101663 | (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride | (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE | (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylide | ||
| CAS number | 135620-04-1 | molecular formula | [[[(CH3)3C]2C6H2-2-(O-)CH=N]2C6H10]MnCl |
| molecular weight | 635.20 g/mol | Exact mass | ≥98% |
| PSA | 65.200 Ų | logp | - |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram：
GHS07
Signal word：
Warning
Hazard Statement：
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激
Statement of Preventive Measures：
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染：用水充分清洗。 P321: 特殊处理（请参阅此标签上的...）。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P304+P340: 如误吸入：将人转移
WGK Germany：
3
Personal protective equipment：
dust mask type N95 (US)， Eyeshields， Gloves
Production methods and uses
No production method and use information yet
Related
upstream information
No upstream information yet
downstream information
No downstream information yet
MSDS
Found 1 shareMSDS
135620-04-1 | (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1 ,2-cyclohexanediaminomanganese(III) chloride.pdf
