已有报道称3H-1,2-苯并二磺酚-3-酮可与三苯基膦反应生成二硫代水杨基内酯。3H-1,2-苯并二磺酚-3-酮是杂环合成砌块。 应用 在制备含硫代磷酸酯的寡脱氧核糖核苷酸时,可以使用3H-1,2-苯二硫基-3-酮作为硫化试剂。3H-1,2-苯并二磺酚-3-酮(1,2-苯并二磺酚-3-酮)可用作硫转移剂,用于将H-膦硫代酸酯和H-膦酸酯二酯转化为相应的二硫代和单硫代磷酸酯。 3H-1,2-Benzodithiol-3-one is a heterocyclic building block.3H-1,2-Benzodithiol-3-one is reported to react with triphenylphosphine to afford dithiosalicylide.3H-1,2-Benzodithiol-3-one (1,2-benzodithiol-3-one) may be used as sulfur-transferring agent for the transformation ofH-phosphonothioate andH-phosphonate diesters into the corresponding phosphorodi- and phosphoromonothioates.3H-1,2-Benzodithiol-3-one may be employed as sulfurizing reagent in the preparation of phosphorothioate-containing oligodeoxyribonucleotides.
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3H-1,2-Benzodithiol-3-one
Dangerous GoodsCAS number:1677-27-6 molecular formula:C7H4OS2
overview
compound introduction
Specs
| Chinese alias | - | ||
| English alias | 3H-1,2-Benzodithiol-3-one | EINECS 216-829-8 | 1,2-BENZODISULFOL-3-ONE | 3H-Benzo-1,2-dithiol-3-one | DTXSID20168358 | BAA67727 | J-010390 | W18739 | A858146 | 3H-1,2-Benzodithiol-3-one, 97% | 1,2-benzodithiol-3-one | 2SN20K238G | Q27255550 | AKOS01588929 | ||
| CAS number | 1677-27-6 | molecular formula | C7H4OS2 |
| molecular weight | 168.24 g/mol | Exact mass | ≥97% |
| PSA | 67.700 Ų | logp | 2 |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
Signal word:
Warning
Hazard Statement:
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H302: 吞食有害
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
WGK Germany:
3
Personal protective equipment:
Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Production methods and uses
No production method and use information yet
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upstream information
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downstream information
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MSDS
Found 1 shareMSDS
1677-27-6 | 3H-1,2-Benzodithiol-3-one.pdf





