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Bicyclo[2.2.1]hepta-2,5-diene-rhodium chloride dimer

Dangerous Goods

CAS number:12257-42-0    molecular formula:C14H16Cl2Rh2

overview

compound introduction

不对称催化交叉偶联反应催化剂,硅氢化催化剂 Precatalysts for Asymmetric and Cross-Coupling Catalysis,Hydrosilylation Catalysts Catalyst for valence isomerization and N-heterocyclization; incombination with phosphorus ligands are catalysts for hydrogenationof many functional groups and hydroformylation; withchiral ligands are catalysts for asymmetric hydrogenation. Product class M-C, Homogeneous Catalysts, Diene/Dienyl Ligands Reaction type Hydrogenation, Asymmetric Reactions, CH-Activation, Hydroformylation, Asymmetric Hydrogenation, Hydrosilylation, Isomerization Chemical properties Chemical formula C 1 4 H 1 6 Cl 2 Rh 2 Empirical formula [Rh(nbd)Cl] 2 Molecular weight 461.00 Metal Rh Theoretical metal content 45 Physical state crystalline Color orange

Specs

Chinese alias降冰片二烯氯化铑二聚体 | 二氯化二铑(双降冰片二烯) | 氯化降冰片二烯铑二聚物 | 二氯双(降冰片二烯)二铑 | 二氯化二铑(双降冰片二烯) 铑
English aliasChiralyst P461 | EINECS 235-510-4 | (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER | DTXSID10924203 | bicyclo[2.2.1]hepta-2,5-diene;rhodium(2+);dichloride | FT-0696287 | Bis((2,3,5,6-eta)-bicyclo(2.2.1)hepta-2,5-diene)di-mu-chlorodirhodium | Rhodiu
CAS number12257-42-0molecular formulaC14H16Cl2Rh2
molecular weight460.99 g/molExact mass≥96%
PSA-logp-

numbering system

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physicochemical properties

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Safety information

pictogram:
GHS07
Signal word:
Warning
Hazard Statement:
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H413: 可能对水生生物造成长期的有害影响 H302: 吞食有害 H312: 皮肤接触有害 H332: 吸入有害
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P273: 避免释放到环境中。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染:用水充分清洗。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P270
WGK Germany:
3
Personal protective equipment:
Eyeshields, Gloves, type N95 (US)

Production methods and uses

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Related

upstream information

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downstream information

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MSDS

Found 1 shareMSDS
12257-42-0 | Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I)chloride dimer.pdf