三甲基硅氧基钠是一种性能强大的多功能试剂,用于酯转化生成羧酸和腈水解生成伯酰胺。它可作为起始原料用于通过盐复分解合成金属硅醇盐,也可作为催化剂用于硅烷醇和含氢硅烷的硅烷化反应。 应用: 三甲基硅烷醇钠用作以下反应中的催化剂: 硅酸铑配合物的合成。 甲基苯基硅烷与叔丁基二甲基硅烷醇的硅烷化反应合成三硅氧烷 Sodium trimethylsilanolate is a versatile and very powerful reagent for the conversion of esters to carboxylic acids and the hydrolysis of nitriles to primary amides. It can be used as a starting material for the synthesis of metal silanolates via the salt metathesis and as a catalyst for the silylation of silanols with hydrosilanes. Application: Sodium trimethylsilanolate is used as a catalyst in the: Synthesis of the rhodium silonate complex. Silylation of methylphenylsilane with tert-butyldimethylsilanol to synthesize trisiloxanes.
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Sodium trimethylsilanolate
Dangerous GoodsCAS number:18027-10-6 molecular formula:C3H9SiONa
overview
compound introduction
Specs
| Chinese alias | 三甲基硅酸钠 | 三甲基硅醇 钠盐 | ||
| English alias | MFCD00013926 | SCHEMBL380132 | Trimethylsilanol sodium salt | Silanol, 1,1,1-trimethyl-, sodium salt (1:1) | AKOS015909317 | Sodium trimethylsilanolate, 95% | trimethylsilyloxy sodium | sodium trimethylsilanolat | FT-0637638 | NaOTMS | s15125 | SODIUMTRIM | ||
| CAS number | 18027-10-6 | molecular formula | C3H9SiONa |
| molecular weight | 112.18 g/mol | Exact mass | ≥95% |
| PSA | 23.100 Ų | logp | - |
numbering system
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physicochemical properties
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Safety information
pictogram:
GHS05
Signal word:
Danger
Hazard Statement:
H314: 造成严重的皮肤灼伤和眼睛损伤
Statement of Preventive Measures:
P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P301+P330+P331: 如误吞咽:漱口。不要诱导呕吐。 P304+P340: 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。 P363: 再次使用之前,请清洗受污染的衣物。 P305+P354+P338: 如果进入眼睛:立即用水冲洗几分钟
WGK Germany:
3
Production methods and uses
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downstream information
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MSDS
Found 1 shareMSDS
18027-10-6 | Sodium trimethylsilanolate.pdf





