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(-)-α-Phellandrene

Dangerous Goods

CAS number:4221-98-1    molecular formula:C10H16

overview

compound introduction

(R)-(-)-α-水芹烯是一种单萜衍生物。 应用 (R)-(-)-α-水芹烯可与2-萘基乙炔羧酸进行[4+2]环加成反应形成手性二烯,其可作为铑催化的不对称加成反应的配体。它可用于合成(1S,5R)-5-(1-甲基乙基)-2-亚甲基-3-环己烯-1-基氢过氧化物,还原形式为 反式-yabunikkeol。 Product Description: (R)-(-)-α-Phellandrene is a monoterpene derivative. Product Application: (R)-(-)-α-Phellandrene undergoes [4+2] cycloaddition with 2-naphthyl acetylenecarboxylate to form a chiral diene, which can act as a ligand for the rhodium-catalyzed asymmetric addition reactions. It may be used to synthesize (1S,5R)-5-(1-methylethyl)-2-methylidene-3-cyclohexen-1-yl hydroperoxide, which on reduction forms trans-yabunikkeol.

Specs

Chinese alias(R)-5-异丙基-2-甲基-1,3-环己二烯
English alias(-)-(r)-alpha-phellandrene | L-.ALPHA.-PHELLANDRENE | EINECS 224-167-6 | 1,3-Cyclohexadiene, 2-methyl-5-(1-methylethyl)-, (theta)- | UNII-56UV8X65K0 | (-)-p-Mentha-1,5-diene | (R)-5-Isopropyl-2-methyl-1,3-cyclohexadiene | trans-3-Hexenoic acid, 97% | .ALP
CAS number4221-98-1molecular formulaC10H16
molecular weight136.24 g/molExact mass-
PSA0.000 Ųlogp3.200

numbering system

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physicochemical properties

No physical and chemical property information yet

Safety information

pictogram:
GHS02
Signal word:
Warning
Hazard Statement:
H226: 易燃液体和蒸气 H304: 吞咽并进入呼吸道可能致命
Statement of Preventive Measures:
P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370+P378: 火灾时:使用干砂、干粉或抗醇泡沫灭火。 P210: 远离热源,热表面,火花,明火和其他点火源。 - 禁止抽烟。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P233: 保持容器密闭。 P240: 地面/粘结容器和接收设备 P403+P235: 存放在通风良好的地方。保持低温。 P303+P361+P353: 如皮肤(或头发)沾染:立即脱掉所有沾染的衣服。用水清洗皮肤/淋浴。 P241: 使用防爆的[电气/通

Production methods and uses

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Related

upstream information

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downstream information

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MSDS

Found 1 shareMSDS
4221-98-1 | (R)-(−)-α-Phellandrene.pdf