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9-Phenanthrylmagnesium bromide

Dangerous Goods

CAS number:71112-64-6    molecular formula:C14H9BrMg

overview

compound introduction

Description 9-phenanthrylmagnesium bromide is a Grignard reagent. It can be prepared using magnesium turnings and 9-bromophenanthrene under anhydrous condition.9-Phenanthrylmagnesium bromide can be used as a reagent to prepare:9-alkyl and 9-arylthiophenanthrenes by reacting with alkyl or aryl thiol compounds.(S)-α-methylbenzyl 1-(9-phenanthryl)-2-naphthoate by treating with (S)- α -methylbenzyl methoxy-2-naphthoate.1-(9-Phenanthryl)-1-phenylethanol (carbinol) by reacting with acetophenone. The obtained carbinol undergoes dehydration reaction in the presence of acetic acid and sulfuric acid to afford 1-(9-phenanthryl)-1-phenylethene (PPE).

Specs

Chinese alias-
English alias-
CAS number71112-64-6molecular formulaC14H9BrMg
molecular weight281.43 g/molExact mass-
PSA-logp-

numbering system

No numbering system information yet

physicochemical properties

No physical and chemical property information yet

Safety information

pictogram:
GHS08 , GHS07 , GHS02
Signal word:
Danger
Hazard Statement:
H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H351: 怀疑引起遗传缺陷 H302: 吞食有害 H225: 高度易燃的液体和蒸气
Statement of Preventive Measures:
P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370+P378: 火灾时:使用干砂、干粉或抗醇泡沫灭火。 P210: 远离热源,热表面,火花,明火和其他点火源。 - 禁止抽烟。 P403+P235: 存放在通风良好的地方。保持低温。 P301+P312+P330: 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口
UN Number:
2924

Production methods and uses

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Related

upstream information

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downstream information

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MSDS

Found 1 shareMSDS
71112-64-6 | 9-Phenanthrylmagnesium bromide.pdf