应用: 氯化镍(II)乙二醇二甲基醚络合物可用于: 用作外消旋苄基氯的硼化反应的催化剂,以合成对映体富集的苄基硼酸酯。 用作烷基碘的三氟甲基化的启动剂,以合成多种烷基CF3化合物。 合成双(苯并咪唑-2-亚苄基)镍钳形配合物,可用于将CO2电催化还原为CO。 用作路易斯酸催化剂,通过可见光的光活化作用C-酰化β-酮酸酯。 Application: Nickel(II) chloride ethylene glycol dimethyl ether complex can be used: As a catalyst for the borylation of racemic benzylic chloride to synthesize enantioenriched benzylic boronic esters. As a promoter for the trifluoromethylation of alkyl iodides to synthesize broad range of alkyl-CF3 compounds. For the synthesis of nickel bis(benzimidazol-2-ylidene) pincer complexes which can be used for electrocatalytic reduction of CO2 to CO. As a Lewis acid catalyst for C-acylation β-ketoesters through photoactivation by visible light.
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dichloronickel,1,2-dimethoxyethane
Dangerous GoodsCAS number:29046-78-4 molecular formula:NiCl2:CH3OCH2CH2OCH3
overview
compound introduction
Specs
| Chinese alias | 氯化镍(II)乙二醇二甲基醚络合物 | NiCl2 甘醇二甲醚 | 二氯(二甲氧基乙烷)镍 | 氯化镍(II)乙二醇二甲醚 | ||
| English alias | FT-0638826 | MFCD00013481 | A903139 | Dichloro(dimethoxyethane)nickel | dichloronickel,1,2-dimethoxyethane | dichloronickel;1,2-dimethoxyethane | OCMNCWNTDDVHFK-UHFFFAOYSA-L | nickel(II) chloride dimethoxyethane | SCHEMBL1486833 | nicl2(dme) | NICKEL(II) | ||
| CAS number | 29046-78-4 | molecular formula | NiCl2:CH3OCH2CH2OCH3 |
| molecular weight | 219.72 g/mol | Exact mass | ≥98% |
| PSA | 18.500 Ų | logp | - |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram:
GHS06 , GHS08 , GHS09 , GHS07 , GHS02
Signal word:
Danger
Hazard Statement:
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H301: 吞咽会中毒 H334: 吸入可能引起过敏或哮喘病症状或呼吸困难 H400: 对水生生物有剧毒 H350: 可能导致癌症 H261: 与水接触释放出易燃气体
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P273: 避免释放到环境中。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P231+P232: 在惰性气体中操作。防潮。 P370+P378: 火灾时:使用干砂、干粉或抗醇泡沫灭火。 P302+P352: 如皮肤沾染:用水充分清洗。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将
WGK Germany:
3
Personal protective equipment:
Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Production methods and uses
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downstream information
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MSDS
Found 1 shareMSDS
29046-78-4 | Nickel(II) chloride ethylene glycol dimethylether complex.pdf





