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(+)-2,2′-Isopropylidenebis[(4R)-4-phenyl-2-oxazoline]

Dangerous Goods

CAS number:150529-93-4    molecular formula:C21H22N2O2

overview

compound introduction

application: (+)-2,2′-Isopropylidenebis[(4R)-4-phenyl-2-oxazoline] in the presence of copper iodide, can catalyze the asymmetric cyclopropanation reaction of phenyliodonium ylides with alkenes to form cyclopropane α-amino acid esters. C2 symmetric ligand for enantioselective catalysis. Easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals.

Specs

Chinese alias(R,R)-2,2'-异亚丙基双(4-苯基-2-恶唑啉) | (R,R)-2,2-双(4-苯基-2-恶唑啉-2-基)丙烷 | (R,R)-2,2'-(二甲基亚甲基)双(4-苯基-2-恶唑啉) | (+)-2,2'-异亚丙基双[(4R)-4-苯基-2-噁唑啉] | (R,R)-2,2'-异亚丙基双(4-苯基-2-噁唑啉) | (R,R)-2,2'-双(4-苯基-2-噁唑啉-2-基)丙烷
English alias(R,R)-Ph-box | AMY25577 | Oxazole, 2,2'-(1-methylethylidene)bis(4,5-dihydro-4-phenyl-, (4R,4'R)- | (R,R)-2,2'-Bis(4-phenyl-2-oxazolin-2-yl)propane | (R,R)-2,2-Bis(4-phenyl-2-oxazolin-2-yl)propane | 2,2-bis[(4r)-4-phenyl-1,3-oxazolin-2-yl] propane | T70318
CAS number150529-93-4molecular formulaC21H22N2O2
molecular weight334.41 g/molExact mass≥96%
PSA43.200 Ųlogp3.800

numbering system

No numbering system information yet

physicochemical properties

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Safety information

pictogram:
GHS06
Signal word:
Danger
Hazard Statement:
H301: 吞咽会中毒 H311: 皮肤接触有毒 H331: 吸入会中毒 H301+H311+H331: 吞咽、皮肤接触或吸入中毒。
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染:用水充分清洗。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P270: 使用本产品时,请勿进食、饮水或吸烟。 P304+P340: 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。 P403+P233: 存放在通风良
WGK Germany:
3
Personal protective equipment:
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Production methods and uses

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Related

upstream information

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downstream information

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MSDS

Found 1 shareMSDS
150529-93-4 | (+)-2,2′-Isopropylidenebis[(4R)-4-phenyl-2-oxazoline].pdf