氯二(2-呋喃基)膦是一种反应物,可用于合成生硬甾体的1,3-二齿二茂铁基二膦配体,二茂铁基手性二膦和含膦的氨基酸。此外,氯二(2-呋喃基)膦可用作醛的α-芳基化反应,无环烯丙基亚膦酸酯的立体选择性[2,3]σ重排以及官能化烯烃的氢磷酸化的反应物。 Chlorodi(2-furyl)phosphine is a reactant that is used in the synthesis of centrostereogenic 1,3-bidentate ferrocenyldiphosphane ligands, Ferrocene-based chiral diphosphine, and phosphine containing amino acids. In addition, Chlorodi(2-furyl)phosphine can be used as a reactant for α-Arylation of aldehydes, stereoselective [2,3] sigmatropic rearrangement of acyclic allylic phosphinites and hydrophosphination of functionalized alkenes.
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Chlorodi(2-furyl)phosphine
Dangerous GoodsCAS number:181257-35-2 molecular formula:C8H6ClO2P
overview
compound introduction
Specs
| Chinese alias | - | ||
| English alias | Bis(2-furyl)phosphine chloride, 85% | Di-2-furanylphosphinous chloride | SCHEMBL1784193 | J-011577 | Bis(2-furyl)phosphine chloride | Phosphinous chloride, P,P-di-2-furanyl- | chlorodifuran-2-ylphosphine | AKOS015910836 | BIS(2-FURYL)CHLOROPHOSPHINE | Di( | ||
| CAS number | 181257-35-2 | molecular formula | C8H6ClO2P |
| molecular weight | 200.56 g/mol | Exact mass | ≥80% |
| PSA | 26.300 Ų | logp | 2.600 |
numbering system
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physicochemical properties
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Safety information
pictogram:
GHS05 , GHS02
Signal word:
Danger
Hazard Statement:
H314: 造成严重的皮肤灼伤和眼睛损伤 H261: 与水接触释放出易燃气体
Statement of Preventive Measures:
P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P231+P232: 在惰性气体中操作。防潮。 P370+P378: 火灾时:使用干砂、干粉或抗醇泡沫灭火。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P301+P330+P331: 如误吞咽:漱口。不要诱导呕吐。 P304+P340: 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。 P
WGK Germany:
3
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MSDS
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