Catalyst for: 1Cu / diphosphine-catalyzed asymmetric hydrogenation of heteroaromatic ketones and enones 2Highly selective rhodium-catalyzed hydrogenation reactions 3 Classical versus kinetic resolution in preparation of privileged silicon-stereogenic silanaphthalenes. Used for kinetic resolution of donor-functionalized secondary alcohols via Cu-H-catalyzed stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes. Used for comparative studies of conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis. Catalyst for: 1Cu / diphosphine-catalyzed asymmetric hydrogenation of heteroaromatic ketones and enones 2Highly selective rhodium-catalyzed hydrogenation reactions 3 Classical versus kinetic resolution in preparation of privileged silicon-stereogenic silanaphthalenes. Used for kinetic resolution of donor-functionalized secondary alcohols via Cu-H-catalyzed stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes. Used for comparative studies of conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis.
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Tris(3,5-dimethylphenyl)phosphine
Dangerous GoodsCAS number：69227-47-0 molecular formula：[(CH3)2C6H3]3P
overview
compound introduction
Specs
| Chinese alias | - | ||
| English alias | AS-61267 | MFCD03094579 | AKOS015914585 | Tris(3,5-dimethylphenyl)phosphine, 96% | p(3,5-xylyl)3 | A836402 | DTXSID5071969 | F17206 | SCHEMBL503226 | Tri-3,5-xylylphosphine | tris(3,5-dimethylphenyl)phosphane | tris(3,5-xylyl) phosphine | Tris(3,5-dimethy | ||
| CAS number | 69227-47-0 | molecular formula | [(CH3)2C6H3]3P |
| molecular weight | 346.44 g/mol | Exact mass | ≥96% |
| PSA | 0.000 Ų | logp | 6.800 |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram：
GHS07
Signal word：
Warning
Hazard Statement：
H302: 吞食有害
Statement of Preventive Measures：
P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P270: 使用本产品时，请勿进食、饮水或吸烟。 P330: 漱口 P301+P317: 如果被吞咽：请寻求医疗帮助。
WGK Germany：
3
Personal protective equipment：
dust mask type N95 (US), Eyeshields, Gloves
Production methods and uses
No production method and use information yet
Related
upstream information
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downstream information
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MSDS
Found 1 shareMSDS
69227-47-0 | Tris(3,5-dimethylphenyl)phosphine.pdf
