在空气中不稳定,有腐蚀性。遇水分解,形成PbO 2 和醋酸,溶于热冰乙酸、苯、氯仿、四氯化碳、甲苯、乙腈、硝基苯和二氯甲烷。有毒。无水醋酸液封。有机合成中的选择性氧化剂。诱导二氟二碘甲烷加成到烯烃和炔烃上。 Lead(IV) acetate is an inorganic lead salt. It participates in α-acetoxylation of ketones and oxidative decarboxylation of carboxylic acids. It along with an ionic halide (particularly chloride) salt participates in the decarboxylation of acids to afford alkyl chlorides. It affords the corresponding α,β-unsaturated γ-acetoxy-γ-lactones via reaction with 2-(trimethylsiloxy)furans.
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Lead(IV) acetate
Dangerous GoodsCAS number:546-67-8 molecular formula:Pb(CH3CO2)4
overview
compound introduction
Specs
| Chinese alias | 乙酸铅(IV) | 乙酸高铅 | 醋酸高铅 | 乙酸高铅盐 | 四醋酸铅 | ||
| English alias | lead (IV) tetra acetate | lead tetra-acetate | Lead tetracetate | Lead (IV) Acetate | Tetrakis(acetato-kappaO,kappaO')lead | AKOS025243798 | DTXSID801047756 | Lead (IV) Aceate | Lead (IV) tetraacetate | lead (IV) tetra-acetate | C8H12O8Pb | L0021 | ||
| CAS number | 546-67-8 | molecular formula | Pb(CH3CO2)4 |
| molecular weight | 443.38 g/mol | Exact mass | AR |
| PSA | 161.000 Ų | logp | - |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram:
GHS08 , GHS07 , GHS03
Signal word:
Danger
Hazard Statement:
H373: 通过长时间或反复暴露对器官造成损害 H302: 吞食有害 H400: 对水生生物有剧毒 H332: 吸入有害 H410: 对水生生物有剧毒并具有长期持续影响 H360: 可能损害生育力或未出生的孩子
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P273: 避免释放到环境中。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P271: 仅在室外或通风良好的地方使用。 P270: 使用本产品时,请勿进食、饮水或吸烟。 P304+P340: 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。 P391: 收集溢出物 P330: 漱口 P2
WGK Germany:
3
Personal protective equipment:
Eyeshields,Faceshields,full-face particle respirator type N100 (US),Gloves,respirator cartridge type N100 (US),type P1 (EN143) respirator filter,type P3 (EN 143) respirator cartridges
RTECS:
AI5300000
UN Number:
2291
Packing Group:
III
Production methods and uses
No production method and use information yet
Related
upstream information
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downstream information
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MSDS
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