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Diethylzinc solution

Dangerous Goods

CAS number:557-20-0(hexane)    molecular formula:C4H10Zn

overview

compound introduction

和水发生爆炸性剧烈反应,可安全地溶于干燥的饱和脂肪烃及芳烃溶剂。 低浓度蒸气在空气中发烟,如产品曝露在空气中则自燃和Rh (I) 催化剂一起用于从α,β-非饱和酮制备α-三氟甲基酮。 Employed together with a Rh (I) catalyst to prepare α-trifluoromethyl ketones from α,β-unsaturated ketones. Diethylzinc solution can be used as a reagent to prepare: • α-trifluoromethyl ketones from α, β-unsaturated ketones with Rh (I) catalyst. • Alkynylzinc reagents which are used in cross-coupling reactions. • Chiral secondary alcohols from aromatic and aliphatic aldehydes in presence of camphor-derived β-amino alcohol. • 1, 4 conjugate addition product with enones. • α-fluoroacrylates from aldehydes and ketones.

Specs

Chinese alias-
English aliasAC-1790 | EINECS 209-161-3 | (C2H5)2Zn | DTXSID4052217 | MFCD00009021 | HQWPLXHWEZZGKY-UHFFFAOYSA-N | Zinkdiethyl | Diethylzinc, purum, >=95.0% (KT) | Zinc diethyl | Zn(C2H5)2 | AKOS009145267 | Diethylzinc, elec. gr. | zinc;ethane | CHEBI:51496 | UNII-S0W
CAS number557-20-0(hexane)molecular formulaC4H10Zn
molecular weight123.51 g/molExact mass1.0 M in Hexane
PSA0.000 Ųlogp-

numbering system

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physicochemical properties

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Safety information

pictogram:
GHS08 , GHS09 , GHS05 , GHS07 , GHS02
Signal word:
Danger
Hazard Statement:
H373: 通过长时间或反复暴露对器官造成损害 H411: 对水生生物有毒并具有长期持续影响 H260: 与水接触会释放出可自燃的易燃气体 H314: 造成严重的皮肤灼伤和眼睛损伤 H318: 造成严重的眼睛损伤 H225: 高度易燃的液体和蒸气 H250: 暴露在空气中会自燃 H304: 吞咽并进入呼吸道可能致命 H401: 对水生生物有毒 H361: 怀疑破坏生育力或未出生的孩子
Statement of Preventive Measures:
P273: 避免释放到环境中。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P301+P310: 如误吞咽:立即呼叫急救中心/医生。 P223: 不允许与水接触 P370+P378: 火灾时:使用干砂、干粉或抗醇泡沫灭火。 P210: 远离热源,热表面,火花,明火和其他点火源。 - 禁止抽烟。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P240: 地面/粘结容器和接收设备 P264: 处理后要彻底洗手。 P403+P235: 存放在通风良好的地方。保持低温。 P260:
UN Number:
3399
General hazardous chemicals:
一般危化品
Packing Group:

Production methods and uses

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