溴代硝基甲烷已被用于: · 生产各种受保护的α-溴代硝基烷烃供体(包括Fmoc),用于Umpolung酰胺合成 · 通过碘化钠催化的亨利反应,制备(Z)-1-溴-1-硝基烯烃 · 通过domino Michael加成/分子内烷基化策略,用于β,γ-不饱和a-酮酯的非对映体和对映体选择性环丙烷化反应中 Bromonitromethane has been used: · in production of various protected α-bromo nitroalkane donors (including Fmoc) for use in Umpolung amide synthesis · in preparation of (Z)-1-bromo-1-nitroalkenes via sodium iodide-catalyzed Henry reaction · in diastereo- and enantioselective cyclopropanation of β,γ-unsaturated a-ketoesters via domino Michael-addition/intramolecular-alkylation strategy
All
Chemical Reagents
Biomedicine
Organic raw materials
Inorganic chemical industry
intermediate
Agricultural chemicals
Auxiliaries and catalysts
Fragrances and Flavors
Dyes and Pigments
Daily chemical industry
Bromonitromethane
Dangerous GoodsCAS number:563-70-2 molecular formula:CH2BrNO2
overview
compound introduction
Specs
| Chinese alias | - | ||
| English alias | 1-bromonitromethane | EG63P9EUR0 | Methane, bromonitro- | Nitrobromomethane | Bromonitromethane | bromo-nitromethane | Bromo-nitro-methane | CCRIS 9456 | monobromonitromethane | bromo(nitro)methane | UNII-EG63P9EUR0 | α-Bromonitromethane | CHEMBL2335229 | | ||
| CAS number | 563-70-2 | molecular formula | CH2BrNO2 |
| molecular weight | 139.94 g/mol | Exact mass | 无水级 |
| PSA | 45.800 Ų | logp | 0.900 |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram:
GHS07 , GHS03
Signal word:
Warning
Hazard Statement:
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H272: 可能加剧火灾; 氧化剂
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370+P378: 火灾时:使用干砂、干粉或抗醇泡沫灭火。 P210: 远离热源,热表面,火花,明火和其他点火源。 - 禁止抽烟。 P302+P352: 如皮肤沾染:用水充分清洗。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/
WGK Germany:
3
Personal protective equipment:
Eyeshields,full-face particle respirator type N100 (US),Gloves,respirator cartridge type N100 (US),type P1 (EN143) respirator filter,type P3 (EN 143) respirator cartridges
RTECS:
PA5360000
UN Number:
3139
Production methods and uses
No production method and use information yet
Related
upstream information
No upstream information yet
downstream information
No downstream information yet
MSDS
Found 1 shareMSDS
563-70-2 | Bromonitromethane.pdf





