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Benzeneselenol

Dangerous Goods

CAS number:645-96-5    molecular formula:C6H5SeH

overview

compound introduction

苯硒醇是一种芳基硒醇。本文报道了二苯基二硒醚在钨灯照射下能促进苯硒醇自由基加成到灭活的乙炔上。报道了苯乙烯醇催化锡烷介导的自由基链反应,通过二苯基二硒醚与氢化三丁基锡的还原反应原位生成。 在单烯烃基取代的1,3-二烯的合成中,苯砜可以用作起始试剂。可用于合成阳离子硫醇桥联二钌配合物。 Benzeneselenol is an aryl selenol. Diphenyl diselenide-promoted radical addition of benzeneselenol to inactivated acetylenes upon irradiation through Pyrex with a tungsten lamp has been reported Catalysis of stannane-mediated radical chain reactions by benzeneselenol, generated in situ by reduction of diphenyl diselenide with tributyltin hydride, has been reporte Benzeneselenol may be used as starting reagent in the synthesis of monoseleno-substituted 1,3-dienes.It may be used in the synthesis of cationic chalcogenolato-bridged diruthenium complexes

Specs

Chinese alias苯硒醇
English aliasHydroselenobenzene | PhSeH | EINECS 211-457-2 | Benzeneselenol | MFCD00000001 | AKOS015840368 | ?PHENYLSELENOL | Phenylselenium | Phenol, seleno- | GXE | Benzene, selenyl- | B2105 | YWBHROUQJYHSOR-UHFFFAOYSA-N | Benzeneselenol, 97% | DTXSID30275709 | Phen
CAS number645-96-5molecular formulaC6H5SeH
molecular weight157.07 g/molExact mass≥97%
PSA0.000 Ųlogp-

numbering system

No numbering system information yet

physicochemical properties

No physical and chemical property information yet

Safety information

pictogram:
GHS06 , GHS08 , GHS09
Signal word:
Danger
Hazard Statement:
H301: 吞咽会中毒 H331: 吸入会中毒 H373: 通过长时间或反复暴露对器官造成损害 H400: 对水生生物有剧毒 H410: 对水生生物有剧毒并具有长期持续影响
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P273: 避免释放到环境中。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P271: 仅在室外或通风良好的地方使用。 P270: 使用本产品时,请勿进食、饮水或吸烟。 P304+P340: 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。 P403+P233: 存放在通风良好的地方。保持容器密闭
WGK Germany:
3
Personal protective equipment:
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Production methods and uses

No production method and use information yet

Related

upstream information

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downstream information

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MSDS

Found 1 shareMSDS
645-96-5 | Benzeneselenol.pdf