尿苷和胸苷的N-3保护剂。 丙酸甲酯被用于合成多取代的 3-芳基氨基丙烯酸酯和四氢嘧啶-2-酮衍生物 。也用作毛细管电泳的巯基衍生剂。 在三苯基膦促进的一锅、四组分反应中用于合成1,2,3,5-苯四羧酸。 N-3 protecting reagent for uridines and thymidines. Methyl propiolate was used in the synthesis of polysubstituted 3-arylaminoacrylate and tetrahydropyrimidin-2-one derivatives. It was also used as a thiol derivatizing agent for capillary electrophoresis. Used in a one-pot, four-component synthesis of 1,2,3,5-benzenetetracarboxylates promoted by Ph3P.
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Methyl propiolate
Dangerous GoodsCAS number:922-67-8 molecular formula:C4H4O2
overview
compound introduction
Specs
| Chinese alias | 2-丙炔酸甲酯 | ||
| English alias | NSC 154164 | Propiolic Acid Methyl Ester | 4-02-00-01688 (Beilstein Handbook Reference) | SB40750 | AI3-37828 | MFCD00008572 | InChI=1/C4H4O2/c1-3-4(5)6-2/h1H,2H | AKOS000120024 | methyl propargylate | 2-Propynoic acid, methyl ester | propiolic acid methy | ||
| CAS number | 922-67-8 | molecular formula | C4H4O2 |
| molecular weight | 84.07 g/mol | Exact mass | ≥97% |
| PSA | 26.300 Ų | logp | 0.6 |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram:
GHS07 , GHS02
Signal word:
Danger
Hazard Statement:
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H225: 高度易燃的液体和蒸气
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370+P378: 火灾时:使用干砂、干粉或抗醇泡沫灭火。 P210: 远离热源,热表面,火花,明火和其他点火源。 - 禁止抽烟。 P302+P352: 如皮肤沾染:用水充分清洗。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/
WGK Germany:
3
Personal protective equipment:
Eyeshields,Faceshields,full-face respirator (US),Gloves,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter
RTECS:
UE0050000
UN Number:
3272
Production methods and uses
No production method and use information yet
Related
upstream information
No upstream information yet
downstream information
No downstream information yet
MSDS
Found 1 shareMSDS
922-67-8 | Methyl propiolate.pdf





