接触反应氧化剂,用于碘苯二乙酰氧化橙花醇生成橙花醛。总之,铜/TEMPO用于1位醇生成醛的接触反应。 Catalytic oxidant for copper-catalyzed, greener oxidation of alcohols under aerobic conditions. Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air. TEMPO (2,2,6,6-Tetramethyl-1-piperidinyloxy) was used for trapping the styrenyl radical generated from benzoyl peroxide during nitroxide-mediated radical polymerization of styrene. TEMPO-mediated oxidation was employed for the carboxylation of water-resistant nanofibrillated cellulose (NFC) films.
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TEMPO
Dangerous GoodsCAS number:2564-83-2 molecular formula:C9H18NO
overview
compound introduction
Specs
| Chinese alias | 2,2,6,6-四甲基哌啶氧化物 | 2,2,6,6-四甲基哌啶-N-氧化物 自由基 | 2,2,6,6-四甲基哌啶氧化物 自由基 | ||
| English alias | 2,2,6,6-Tetramethylpiperidine 1-oxyl | TEMPO free radical | 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical | ||
| CAS number | 2564-83-2 | molecular formula | C9H18NO |
| molecular weight | 156.25 g/mol | Exact mass | 升华级 |
| PSA | 4.200 Ų | logp | 1.400 |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram:
GHS05 , GHS07
Signal word:
Danger
Hazard Statement:
H335: 可能引起呼吸道刺激 H314: 造成严重的皮肤灼伤和眼睛损伤 H412: 对水生生物有害并具有长期持续影响 H318: 造成严重的眼睛损伤
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P273: 避免释放到环境中。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P271: 仅在室外或通风良好的地方使用。 P301+P330+P331: 如误吞咽:漱口。不要诱导呕吐。 P304+P340: 如误吸入:将人转移到空气新鲜处,保
WGK Germany:
3
Personal protective equipment:
Eyeshields,Faceshields,full-face particle respirator type N100 (US),Gloves,respirator cartridge type N100 (US),type P1 (EN143) respirator filter,type P3 (EN 143) respirator cartridges
RTECS:
TN8991900
UN Number:
3263
Production methods and uses
No production method and use information yet
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upstream information
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downstream information
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MSDS
Found 1 shareMSDS
2564-83-2 | TEMPO.pdf





