2,5-噻吩二甲酸 (2,5-TDCA,H 2 TDC) 是制备荧光增白剂、杀菌剂和抗癌药物的重要原料。己二酸用氯化亚砜氯化生成。由于其配位方式的多样性,它作为芳香连接物是生成配位网络的极佳选择。用旋转弹燃烧量热法计算了 2,5-噻吩二甲酸的燃烧焓和升华焓。2,5-噻吩二甲酸可作为噻吩基连接基团用于镁配位网络的制备。[6]也可作为合成 2,5-二苯并恶唑噻吩 (EBF) 的前体。 可用于以下合成: · 新型噻吩二甲酸钴配位聚合物 · 新型介晶噻吩类超分子液晶 · 两种新型配位聚合物,分子式为 {[Ln2(2,5-tdc)3(dmso)2]H2O}n (Ln = Tb(III) and Dy(III)), (2,5-tdc2 = 2,5-噻吩二甲酸酯和 dmso = 二甲亚砜) 2,5-Thiophenedicarboxylic acid (2,5-TDCA, H2TDC) is an important building block in the preparation of fluorescent brightening agent, fungicides and anti-cancer drug. It has been generated by chlorination of adipic acid using thionyl chloride.Due to its diverse coordination modes, it is an excellent choice as an aromatic linker to generate coordination networks. The enthalpies of combustion and sublimation of 2,5-thiophenedicarboxylic acid have been evaluated by rotary-bomb combustion calorimetry.
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2,5-Thiophenedicarboxylic acid
Dangerous GoodsCAS number:4282-31-9 molecular formula:C6H4O4S
overview
compound introduction
Specs
| Chinese alias | OB酸 | 2,5-噻吩二羧酸 | 噻酚-2,5-二甲酸 | ||
| English alias | AB01326194-02 | Maybridge4_002021 | YSWG415 | Z56855146 | Q27262737 | DTXSID7063392 | SY005216 | AKOS000592865 | 5Q8A2G9Y8A | SCHEMBL70493 | THIOPHENE-2,5-DICARBOXYLIC ACID | PS-3266 | 2,5-Thiophenedicarboxylic acid, 99% | 2,5-Thiophene dicarboxylic acid | ||
| CAS number | 4282-31-9 | molecular formula | C6H4O4S |
| molecular weight | 172.16 g/mol | Exact mass | ≥98% |
| PSA | 103.000 Ų | logp | 1.3 |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram:
GHS07
Signal word:
Warning
Hazard Statement:
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染:用水充分清洗。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P304+P340: 如误吸入:将人转移
WGK Germany:
3
Personal protective equipment:
dust mask type N95 (US),Eyeshields,Gloves
Production methods and uses
No production method and use information yet
Related
upstream information
No upstream information yet
downstream information
No downstream information yet
MSDS
Found 1 shareMSDS
4282-31-9 | 2,5-Thiophenedicarboxylic acid.pdf





