compound introduction
4-乙烯基-1,3-二氧杂环戊烷-2-酮 (VEC) 是一种环状碳酸酯，可由丙烯醛与硫叶立德和 CO 2 反应合成 。在 2-丙醇存在下，钌催化的 VEC 转移氢化 (TH) 形成 1,2-丁二醇。吲哚和吲哚在铑 (III) 催化剂存在下与 VEC 发生选择性 C-H 烯丙基化反应。 4-Vinyl-1,3-dioxolan-2-one (VEC) is a cyclic carbonate, that can be synthesized from acrolein by reacting with sulfur ylide and CO2.The ruthenium-catalyzed transfer hydrogenation (TH) of VEC in the presence of 2-propanol forms 1,2-butanediol.Indolines and indoles undergo selective C-H allylation with VEC in the presence of rhodium(III) catalyst.
