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2-(Diphenylphosphino)ethylamine

Dangerous Goods

CAS number:4848-43-5    molecular formula:C14H16NP

overview

compound introduction

2-(二苯基膦基)乙胺是一种双齿结构的膦配体,磷原子提供两对孤对电子供金属离子配位。可用作反应剂,合成酰胺化合物选择性氢化反应的活性催化剂。它也被用作合成其他膦配体的前体。 应用: 2-(二苯基膦基)乙胺可用作镍催化体系中的双齿配体,用于炔烃经还原[2+2]环加成合成环丁烯的反应。 2-(Diphenylphosphino)ethylamine is a phosphine ligand that has a bidentate structure with the phosphorus atom donating two lone pair electrons to coordinate with metal atoms. It is used as a reactant to synthesize active catalyst for the selective hydrogenation of amides. In addition, it is also used as a precursor to synthesize other phosphine ligands. Application: 2-(Diphenylphosphino)ethylamine can be used as a bidentate ligand in the nickel catalyst system for the reductive [2+2] cycloaddition reaction to synthesize cyclobutenes from alkynes.

Specs

Chinese alias(2-氨基乙基)二苯基膦 | 1-氨基-2-(二苯基膦基)乙烷
English aliasNSC118384 | NSC-118384 | 2-(diphenylphosphanyl)ethanamine | SY066843 | STL554954 | Ethanamine, 2-(diphenylphosphino)- | FT-0645041 | (2-AMINOETHYL)DIPHENYLPHOSPHINE;1-AMINO-2-(DIPHENYLPHOSPHINO)ETHANE;2-(DIPHENYLPHOSPHINO)ETHANAMINE;2-(DIPHENYLPHOSPHINO)E
CAS number4848-43-5molecular formulaC14H16NP
molecular weight229.26 g/molExact mass≥95%
PSA26.000 Ųlogp2.100

numbering system

No numbering system information yet

physicochemical properties

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Safety information

pictogram:
GHS05
Signal word:
Danger
Hazard Statement:
H314: 造成严重的皮肤灼伤和眼睛损伤
Statement of Preventive Measures:
P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P301+P330+P331: 如误吞咽:漱口。不要诱导呕吐。 P304+P340: 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。 P363: 再次使用之前,请清洗受污染的衣物。 P305+P354+P338: 如果进入眼睛:立即用水冲洗几分钟
WGK Germany:
3
Personal protective equipment:
Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Production methods and uses

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Related

upstream information

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downstream information

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MSDS

Found 1 shareMSDS
4848-43-5 | 2-(Diphenylphosphino)ethylamine.pdf