用于无保护的胸腺嘧啶核苷的巯羰基化。形成保护性核糖核苷(可被三丁基氢化锡还原为脱氧核苷)的苯氧基硫代羰基酯。 Reagent for thionocarbonylation of unprotected thymine nucleosides.Forms phenoxythiocarbonyl esters of protected ribonucleosides which can be reduced by tributyltin hydride to deoxyribonucleosides. application: O-Phenyl chlorothionoformate has been used in: stereodirected synthesis of optically active, (−)-mintlactone synthesis of peptide α-thioesters having a variety of C-terminal amino acids synthesis of scyllo-inositol derivatives
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O-Phenyl chlorothionoformate
Dangerous GoodsCAS number:1005-56-7 molecular formula:C7H5ClOS
overview
compound introduction
Specs
| Chinese alias | 氯甲基硫代苯酯 | 硫代氯甲酸-O-苯酯 | 氯化硫代甲酸苯酯 | ||
| English alias | NCIOpen2_001921 | O-Phenyl chlorothionoformate, 99% | NSC99103 | NSC-99103 | DTXSID40143349 | Carbonochloridothioic acid, O-phenyl ester | phenylchlorothiocarbonate | Oprea1_157766 | SCHEMBL19247 | C7H5ClOS | Formic acid, O-phenyl ester | MFCD00004920 | o | ||
| CAS number | 1005-56-7 | molecular formula | C7H5ClOS |
| molecular weight | 172.63 g/mol | Exact mass | ≥98% |
| PSA | 41.300 Ų | logp | 3.300 |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram:
GHS05
Signal word:
Danger
Hazard Statement:
H314: 造成严重的皮肤灼伤和眼睛损伤
Statement of Preventive Measures:
P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P301+P330+P331: 如误吞咽:漱口。不要诱导呕吐。 P304+P340: 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。 P363: 再次使用之前,请清洗受污染的衣物。 P305+P354+P338: 如果进入眼睛:立即用水冲洗几分钟
WGK Germany:
3
Personal protective equipment:
Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Production methods and uses
No production method and use information yet
Related
upstream information
No upstream information yet
downstream information
No downstream information yet
MSDS
Found 1 shareMSDS
1005-56-7 | O-Phenyl chlorothionoformate.pdf





