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Poly(methylhydrosiloxane)

CAS number:9004-73-3    molecular formula:(CH3)3SiO[(CH3)HSiO]nSi(CH3)3

overview

compound introduction

不溶于水。溶于大多数常见有机溶剂,可能会发生反应。不能用做卤烃溶媒,因为可能在催化或加热时发生卤化氢交换反应 还原剂 作为硼氢化物的替代物,用于还原胺化合成绿色胺。 取代胺和异吲哚酮的合成:用大量可用的AlCl3/PMHS催化还原胺化 使用聚甲基羟基硅氧烷和[RuCl2(芳烃)]2催化剂,温和催化亚胺的氢化硅烷化,最终合成胺 We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is an environmentally benign reducing agent and has been enhanced for catalytic efficiency. Click here for more information. Harnessing the reactivity of poly(methylhydrosiloxane) for the reduction and cyclization of biomass to high-value products We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is an environmentally benign reducing agent and has been enhanced for catalytic efficiency. Click here for more information. Harnessing the reactivity of poly(methylhydrosiloxane) for the reduction and cyclization of biomass to high-value products Reducing agent. Used in greener amine synthesis by reductive amination as an alternative to borohydrides. Synthesis of substituted amines and isoindolinones: catalytic reductive amination using abundantly available AlCl3/PMHS Amine Synthesis through Mild Catalytic Hydrosilylation of Imines using Polymethylhydroxysiloxane and [RuCl2(arene)]2 Catalysts

Specs

Chinese alias聚甲基氢硅氧烷 | 甲基氢硅氧烷聚合物
English aliasSCHEMBL20166 | 2-Methyl-1,2-oxasilinanato | DTXSID20733323
CAS number9004-73-3molecular formula(CH3)3SiO[(CH3)HSiO]nSi(CH3)3
molecular weight115.230 g/molExact mass-
PSA9.200 Ųlogp-

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