溶于氯仿、二氯甲烷，水中分解。对空气和潮湿敏感。 应用 用于不对称和交叉偶联催化的预催化剂 Allylpalladium(II) chloride dimer is employed as catalyst in Heck reaction. It also participates as catalyst in the tandem nucleophilic allylation-alkoxyallylation reaction of the alkynylaldehydes with allyl chloride and allyltributylstannane. Allylpalladium(II) chloride dimer has been employed for the following studies: ● Synthesis of cationic palladium cataysts, used in the microwave-assisted Heck arylation. ● Synthesis of N-heterocyclic carbene-palladium-η3-allyl chloride complexes, which are efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides. ● Synthesis of 1,4-diallyl-1,2-dihydroisoquinolines. ● As catalyst for greener Buchwald-Hartwig coupling in TPGS-750-M. Application Precatalysts for Asymmetric and Cross-Coupling Catalysis Product class M-C, Homogeneous Catalysts, Allyl Ligands Reaction type Cross Coupling Reactions with Arenes, Amination, Allylic Alkylation, Buchwald-Hartwig Aminaton, Asymmetric Reactions, CH-Activation, Mizoroki Heck Coupling Reaction Chemical properties Chemical formula C 6 H 1 0 Cl 2 Pd 2 Empirical formula [Pd(allyl)Cl] 2 Molecular weight 365.89 Metal Pd Theoretical metal content 58 Physical state crystalline Color yellow Metal purity 99.95
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Allylpalladium(II) chloride dimer
Dangerous GoodsCAS number：12012-95-2 molecular formula：C6H10Cl2Pd2
overview
compound introduction
Specs
| Chinese alias | 烯丙基氯化钯(II)二聚体, [氯化钯(C3H5)] 2, \ [氯化钯(烯丙基)] 2, 二烯丙基二氯二钯, 双(烯丙基氯钯), 双(烯丙基)二氯二钯, 双(烯丙基)二氯化钯, 烯丙基氯钯二聚体 | 二-μ-氯双[(η-烯丙基)钯(II)] | ||
| English alias | [Pd(allyl)Cl]2 | Bis((eta3-allyl)(chloro)palladium) | Bis((mu-chloro)(2-propenyl)palladium) | Bis(allyl(mu-chloro)palladium) | Bis(eta3-allyl)dichlorodipalladium | Palladium allyl chloride dimer | MFCD00044874 | Di-mu-chloro-bis(eta-allyl)palladium | Q101 | ||
| CAS number | 12012-95-2 | molecular formula | C6H10Cl2Pd2 |
| molecular weight | 365.89 g/mol | Exact mass | ≥99.95% metals basis |
| PSA | 0.000 Ų | logp | - |
numbering system
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physicochemical properties
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Safety information
pictogram：
GHS07
Signal word：
Warning
Hazard Statement：
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H302: 吞食有害 H317: 可能引起皮肤过敏反应
Statement of Preventive Measures：
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染：用水充分清洗。 P321: 特殊处理（请参阅此标签上的...）。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P270: 使用本产品时，请勿进食、饮水
WGK Germany：
3
Personal protective equipment：
dust mask type N95 (US),Eyeshields,Faceshields,full-face particle respirator type N100 (US),Gloves,respirator cartridge type N100 (US),type P1 (EN143) respirator filter,type P3 (EN 143) respirator cartridges
RTECS：
RT3510000
Production methods and uses
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MSDS
Found 1 shareMSDS
12012-95-2 | Allylpalladium(II) chloride dimer.pdf
