不溶于水,溶于酸。Pd/C 和 Pd(OH)2/C 的加成反应可提高 N- 或 O-脱苄基反应的效率。 在分子内和分子间过程中高效催化芳基碘和芳基溴的直接芳基化反应。 对苄基-氮键的氢解反应特别有效,并且已证明即使对于其他碳负载钯催化剂失效的情况也同样有效。 Addition of Pd/C to Pd(OH)2/C improves the efficiency of N- or O-debenzylation.[2] Effectively catalyzes the direct arylation reactions of aryl iodides and bromides in both intra- and intermolecular processes. Particularly active for hydrogenolysis of benzyl-nitrogen bonds, and has proven successful even where other palladium-on-carbon catalysts have failed.
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Palladium hydroxide on carbon
Dangerous GoodsCAS number:12135-22-7 molecular formula:O2H2Pd
overview
compound introduction
Specs
| Chinese alias | 氢氧化钯炭 | ||
| English alias | AKOS015904338 | palladium hydroxide/carbon | PALLADIUM(2+) DIHYDROXIDE | paIIadium hydroxide on carbon | Pearlmans Catalyst | Pearlman's catalyst | P1528 | DTXSID20923782 | FT-0689167 | PEARLMAN'S CATALYST [MI] | palladiumhydroxide | Pearl man's catalyst | ||
| CAS number | 12135-22-7 | molecular formula | O2H2Pd |
| molecular weight | 140.43 g/mol | Exact mass | 20% Pd(OH)2 |
| PSA | 2.000 Ų | logp | - |
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physicochemical properties
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Safety information
WGK Germany:
3
Personal protective equipment:
Eyeshields,Gloves,type N95 (US),type P1 (EN143) respirator filter
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MSDS
Found 1 shareMSDS
12135-22-7 | Palladium hydroxide on carbon.pdf





