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Pentamethylcyclopentadienyliridium(III) chloride,dimer

Dangerous Goods

CAS number:12354-84-6    molecular formula:C20H30Cl4Ir2

overview

compound introduction

二氯(五甲基环戊二烯基)合铱(III)二聚体被用于交叉偶联和二聚反应的催化剂。 应用 胺和醇借氢合成绿色胺的催化剂。使用氢气进行绿色还原胺化的合作金属-Bronsted酸催化剂的前体。 Pentamethylcyclopentadienyliridium(III) chloride, dimer is utilized as a catalyst in cross-coupling and dimerization reactions. Product class M-C, Homogeneous Catalysts, Arene/Aryl Ligands Reaction type Hydrogenation, Allylic Alkylation, Asymmetric Reactions, CH-Activation, Asymmetric Hydrogenation, Oxidation Chemical properties Chemical formula C 20 H 30 Cl 4 Ir 2 Empirical formula [Ir(C 5 Me 5 )Cl 2 ] 2 Molecular weight 796.70 Metal Ir Theoretical metal content 48 Physical state powder Color red orange

Specs

Chinese alias二氯(五甲基环戊二烯基)合铱(III)二聚体
English aliasChiralyst P797 | iridium(3+);1,2,3,4,5-pentamethylcyclopenta-1,3-diene;tetrachloride | MMAGMBCAIFVRGJ-UHFFFAOYSA-J | Pentamethylcyclopentadienyliridium(III) dichloride dimer [MI] | IRIDIUM, DI-.MU.-CHLORODICHLOROBIS((1,2,3,4,5-.ETA.)-1,2,3,4,5-PENTAMETHYL
CAS number12354-84-6molecular formulaC20H30Cl4Ir2
molecular weight796.7 g/molExact mass≥98%
PSA0.000 Ųlogp-

numbering system

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physicochemical properties

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Safety information

pictogram:
GHS05 , GHS07
Signal word:
Warning
Hazard Statement:
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H413: 可能对水生生物造成长期的有害影响 H302: 吞食有害 H312: 皮肤接触有害 H332: 吸入有害 H290: 可能腐蚀金属
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P273: 避免释放到环境中。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染:用水充分清洗。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P270
WGK Germany:
3
Personal protective equipment:
Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

Production methods and uses

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Related

upstream information

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downstream information

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MSDS

Found 1 shareMSDS
12354-84-6 | Pentamethylcyclopentadienyliridium(III) chlo-ride,dimer.pdf