应用 Umicore预催化剂，用于不对称和交叉偶联催化用作以下反应的催化剂：氧化烯化反应仲醇的C-C键裂解苯酚衍生物的邻位C-H烯化反应吡啶的氧化环化反应苯甲酰胺与醛通过sp2C-H 键的直接官能化发生氧化邻位酰化反应酰胺化反应还原性烷基化反应五甲基环戊二烯基铑 (III) 氯化物二聚体可作为催化剂 用于：氧化烯化反应、仲醇的C-C 键裂解、苯酚衍生物的邻位 C-H 烯化反应、吡啶的氧化环化反应、苯甲酰胺与醛通过 sp2C-H 键的直接官能团化反应与醛类发生氧化邻位酰化反应、还原烷基化反应['Umicore预催化剂，用于不对称和交叉偶联催化 Description Pentamethylcyclopentadienylrhodium(III) chloride dimer can be used as a catalyst for:Oxidative olefination reactionsC-C bond cleavage of secondary alcoholsOrtho C-H olefination of phenol derivativesOxidative annulation of pyridinesOxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2C-H bondAmidation reactionsReductive alkylation reactionsUmicore Precatalysts for Asymmetric and Cross-Coupling CatalysisCatalyst for:Oxidative olefination reactionsC-C bond cleavage of secondary alcoholsOrtho C-H olefination of phenol derivativesOxidative annulation of pyridinesOxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2C-H bondAmidation reactionsReductive alkylation reactions
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Pentamethylcyclopentadienylrhodium(III) chloride dimer
Dangerous GoodsCAS number：12354-85-7 molecular formula：[Rh(C5Me5)Cl2]2
overview
compound introduction
Specs
| Chinese alias | - | ||
| English alias | Bis(pentamethylcyclopentadienylrhodium dichloride), Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium, Bis(dichloro(pentamethylcyclopentadienyl)rhodium), 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex, Dichloro(pentamethylcyclopentadienyl | ||
| CAS number | 12354-85-7 | molecular formula | [Rh(C5Me5)Cl2]2 |
| molecular weight | 618.08 g/mol | Exact mass | ≥97% |
| PSA | - | logp | - |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram：
GHS07
Signal word：
Warning
Hazard Statement：
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H302+H312+H332: 吞咽，皮肤接触或吸入有害。
Statement of Preventive Measures：
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P501: 将内容物/容器处理到。。。 P312: 打电话给毒物中心或医生。。。如果你觉得不舒服 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P270: 使用本产品时，请勿进食、饮水或吸烟。 P304+P340: 如误吸入：将人转移到空气新鲜处，
WGK Germany：
3
Personal protective equipment：
dust mask type N95 (US), Eyeshields, Gloves
Production methods and uses
No production method and use information yet
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upstream information
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downstream information
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MSDS
Found 1 shareMSDS
12354-85-7 | Pentamethylcyclopentadienylrhodium(III)chloride dimer.pdf
