硼烷二甲硫醚络合物 (BMS) 在催化四氢硼酸钠存在下用作α-羟基酯作为高效和选择性还原剂。已有关于使用螺硼酸酯作为催化剂用 BMS 不对称硼烷还原各种前手性酮的报道。 用作区域选择性还原剂的反应物 涉及的反应物： · 硼氢化/氧化 笼状化合物的合成 硼烷二甲基硫醚复合物 (BMS) 溶液可用于以下研究： · 炔烃一锅转化为 1,2-二醇。 · 亚氨基喷替醇的制备。 · 还原代表性有机官能团，如酯、腈和酰胺。 · 与树枝状聚合物支持的 L-吡咯烷醇一起用于茚满酮和四氢萘酮的不对称还原。 · 二茂铁基-1,3-二酮不对称还原为手性1,3-二醇。 · C3-对称三足羟基酰胺催化的酮的高度对映选择性还原。 Borane dimethyl sulfide complex is a stable source of borane used in hydroboration reduction reactions in organic synthesis. Studies indicate that Borane dimethyl sulfide complex can selectively suppress &alpha-hydroxyesters. Used with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones. CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to chiral 1,3-diols. Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides. Reactant used as a regioselective reducing agent Reactant involved in: &bull Hydroboration / oxidation Synthesis of cage compounds
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Borane dimethyl sulfide complex
Dangerous GoodsCAS number：13292-87-0 molecular formula：(CH3)2S·BH3
overview
compound introduction
Specs
| Chinese alias | 二甲硫醚硼烷 | ||
| English alias | BMS | MCQRPQCQMGVWIQ-UHFFFAOYSA-N | Dimethyl sulphide borane | Dimethyl sulfide borane | borane methylsulphide | boron dimethyl sulfide | FT-0652013 | Borane dimethyl sulfide complex 2.0 M in THF | UNII-93TWS7F2GX | (Dimethyl sulfide)trihydroboron | (Meth | ||
| CAS number | 13292-87-0 | molecular formula | (CH3)2S·BH3 |
| molecular weight | 75.97 g/mol | Exact mass | 2.0 M solution in TH |
| PSA | 25.300 Ų | logp | - |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram：
GHS06 , GHS05 , GHS02
Signal word：
Danger
Hazard Statement：
H315: 引起皮肤刺激 H335: 可能引起呼吸道刺激 H260: 与水接触会释放出可自燃的易燃气体 H318: 造成严重的眼睛损伤 H225: 高度易燃的液体和蒸气 H301+H311: 吞咽或皮肤接触可致中毒。
Statement of Preventive Measures：
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P223: 不允许与水接触 P231+P232: 在惰性气体中操作。防潮。 P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P422: 将内容存储在... P210: 远离热源，热表面，火花，明火和其他点火源。 - 禁止抽烟。
WGK Germany：
3
Personal protective equipment：
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Production methods and uses
No production method and use information yet
Related
upstream information
No upstream information yet
downstream information
No downstream information yet
MSDS
Found 1 shareMSDS
13292-87-0 | Borane dimethyl sulfide complex.pdf
