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Rhodium(III) acetylacetonate

Dangerous Goods

CAS number:14284-92-5    molecular formula:[CH3COCH=C(O-)CH3]3Rh

overview

compound introduction

Rhodium(III) acetylacetonate is a yellowcrystalline compound composed of rhodium atoms coordinated with three acetylacetonate ligands. It iswidely used in the field of catalysis, organic electronics and to prepare Rhcomplexes. It is soluble inorganic solvents. Application: Rhodium(III) acetylacetonate can be used: As a precursor to synthesize Rh nanocrystals with catalytic activities;As an efficient catalyst for the α-alkylation of ketones, β-alkylation of secondary alcohols, and the alkylation of amines with primary alcohols;To prepare highly phosphorescent complexes for organic light-emitting devices;To synthesize the Rh2P NCs supported on carbon (Rh2P/C) by a one-step solvothermal method via a direct reaction between Rh(acac)3 and tri-n-octylphosphine (TOP). The resultant electrocatalyst exhibited remarkable performance for both the hydrogen evolution reaction and the oxygen evolution reaction, surpassing the capabilities of Rh/C and Pt/C catalysts for water splitting;To prepare Single-atom Rh/N-doped carbon electrocatalyst for the oxidation of formic acid;To synthesize Pt–Rh NWs as highly efficient electrocatalysts toward ethanol oxidation reaction (EOR) for Direct ethanol fuel cells. The electrocatalyst demonstrated improved catalytic activities, primarily attributed to the presence of Rh, which enhances its ability to resist poisoning.

Specs

Chinese alias2,4-戊二酮 铑(III) 衍生物
English alias(E)-4-hydroxypent-3-en-2-one;rhodium | Rhodium acetylacetonate | MFCD00083144 | Rhodium(III) 2,4-pentanedionate, Premion(R) | AKOS025311441 | Rh(acac)3 | 2,4-Pentanedione rhodium(III) derivative
CAS number14284-92-5molecular formula[CH3COCH=C(O-)CH3]3Rh
molecular weight400.23 g/molExact mass-
PSA-logp-

numbering system

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physicochemical properties

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Safety information

pictogram:
GHS08 , GHS07
Signal word:
Warning
Hazard Statement:
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H302: 吞食有害 H312: 皮肤接触有害 H332: 吸入有害 H361: 怀疑破坏生育力或未出生的孩子
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染:用水充分清洗。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P270: 使用本产品时,请勿进食、饮水
WGK Germany:
3
Personal protective equipment:
dust mask type N95 (US), Eyeshields, Gloves

Production methods and uses

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Related

upstream information

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downstream information

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MSDS

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14284-92-5 | Rhodium(III) acetylacetonate.pdf