Chlorodicyclohexylphosphine can be used as a reactant in the synthesis of: · 1,2-Bis(dicyclohexylphosphinoxy)ethane ligand by reacting with ethylene glycol in the presence of triethylamine via Michaelis?Arbuzov type rearrangements. · 1,1,2,2-tetracyclohexyldiphosphine monosulfide ligand by treating with LiS. It can be also used as a starting material for the preparation of some other ligands such as dicyclohexylphosphine oxide , phosphino substituted N-aryl pyrroles , di-tert-butyl((dicyclohexylphosphino)methyl)phosphine , dicyclohexylcyclopentylphosphine. These ligands are used in Pd-catalyzed cross-coupling reactions. Chlorodicyclohexylphosphine can be used as a reactant in the synthesis of: · 1,2-Bis(dicyclohexylphosphinoxy)ethane ligand by reacting with ethylene glycol in the presence of triethylamine via Michaelis?Arbuzov type rearrangements. · 1,1,2,2-tetracyclohexyldiphosphine monosulfide ligand by treating with LiS. It can be also used as a starting material for the preparation of some other ligands such as dicyclohexylphosphine oxide , phosphino substituted N-aryl pyrroles , di-tert-butyl((dicyclohexylphosphino)methyl)phosphine , dicyclohexylcyclopentylphosphine. These ligands are used in Pd-catalyzed cross-coupling reactions.
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Chlorodicyclohexylphosphine
Dangerous GoodsCAS number：16523-54-9 molecular formula：(C6H11)2PCl
overview
compound introduction
Specs
| Chinese alias | 二-环己基氯化膦 | 二环己氯化膦 | 二环己氯膦 | 氯代二环己基膦 | 二环己基次膦酰氯 | 二环己基氯膦 | ||
| English alias | CHLORODICYCLOHEXYLPHOSPHANE;CHLORODICYCLOHEXYLPHOSPHINE;DICYCLOHEXYLCHLOROPHOSPHINE;DICYCLOHEXYLPHOSPHINE CHLORIDE;DICYCLOHEXYLPHOSPHINOUS CHLORIDE | Dicyclohexyl(chloro)phosphine | AKOS015914536 | AKJFBIZAEPTXIL-UHFFFAOYSA-N | DTXSID10370140 | chlorodicy | ||
| CAS number | 16523-54-9 | molecular formula | (C6H11)2PCl |
| molecular weight | 232.73 g/mol | Exact mass | ≥97% |
| PSA | 0.000 Ų | logp | 4.3 |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram：
GHS05
Signal word：
Danger
Hazard Statement：
H314: 造成严重的皮肤灼伤和眼睛损伤 H318: 造成严重的眼睛损伤
Statement of Preventive Measures：
P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P321: 特殊处理（请参阅此标签上的...）。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P301+P330+P331: 如误吞咽：漱口。不要诱导呕吐。 P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。 P363: 再次使用之前，请清洗受污染的衣物。 P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。 P
WGK Germany：
3
Personal protective equipment：
Faceshields， full-face respirator (US)， Gloves， Goggles， multi-purpose combination respirator cartridge (US)， type ABEK (EN14387) respirator filter
Production methods and uses
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upstream information
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downstream information
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MSDS
Found 1 shareMSDS
16523-54-9 | Chlorodicyclohexylphosphine.pdf
