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Dichlorobis(trimethylphosphine)nickel(II)

Dangerous Goods

CAS number:19232-05-4    molecular formula:[((CH3)3P)]2NICl2

overview

compound introduction

Catalyst for: 1. Wenkert arylation of thiophene with aryl Grignard reagents 2.Regioselective [2+2+2] cycloaddition of carboryne with alkynes to give benzocarborane compounds 3.Kumada-Corriu cross coupling of Grignard reagents 4.Borylation of aryl chlorides 5.Reductive aldol cyclization-lactonization 6.Arylcyanation of alkynes 7.Alkynylation of benzonitriles via C-C bond activation Catalyst for: 1.Wenkert arylation of thiophene with aryl Grignard reagents 2.Regioselective [2+2+2] cycloaddition of carboryne with alkynes to give benzocarborane compounds 3.Kumada-Corriu cross coupling of Grignard reagents 4.Borylation of aryl chlorides 5.Reductive aldol cyclization-lactonization 6.Arylcyanation of alkynes 7.Alkynylation of benzonitriles via C-C bond activation

Specs

Chinese alias二氯二(三甲基膦)合镍(II)
English aliasF85619 | J-012429 | AKOS015914643 | SC10038 | dichloronickel;trimethylphosphane | Bis(trimethylphosphine)nickel dichloride | FT-0748287 | Dichlorobis(trimethylphosphine)nickel(II), 97% | DTXSID40455934 | Dichlorobis(trimethylphosphine)nickel(II) | SCHEMBL
CAS number19232-05-4molecular formula[((CH3)3P)]2NICl2
molecular weight281.75 g/molExact mass≥97%
PSA0.000 Ųlogp-

numbering system

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physicochemical properties

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Safety information

pictogram:
GHS07
Signal word:
Warning
Hazard Statement:
H302: 吞食有害 H312: 皮肤接触有害 H332: 吸入有害
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染:用水充分清洗。 P321: 特殊处理(请参阅此标签上的...)。 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P270: 使用本产品时,请勿进食、饮水或吸烟。 P304+P340: 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。 P362+P364: 脱掉沾污的衣服,清洗后方可重新使用
WGK Germany:
3
Personal protective equipment:
dust mask type N95 (US), Eyeshields, Gloves

Production methods and uses

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Related

upstream information

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downstream information

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MSDS

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