溶于水,水溶液放置2个月后有80%的内酯转化为葡萄糖醛酸。加热至100℃时,在2h内即有60%的酯和40%的酸达成平衡状态。略溶于甲醇,微溶于乙醇。见光色变深。无臭,味微苦。 应用: D-(+)-葡糖醛酸 γ-内酯可用于以下研究: 在 2,3,4,-三 (叔丁基-二甲基硅烷)葡萄糖醛酸三氯乙酯的合成中作为起始试剂,这种酯是抗炎药 ML-3000 的 1-O-酰基葡糖苷酸的制备中必需的。 光学活性吡喃葡萄糖的合成。 长链烷基呋喃葡萄糖苷的合成。
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D-Glucurone
Dangerous GoodsCAS number:32449-92-6 molecular formula:C6H8O6
overview
compound introduction
Specs
| Chinese alias | 葡醛内酯 | D-葡糖醛酸-γ-内酯 | D-葡糖醛酸内酯 | 葡糖醛酸内酯 | D-葡糖醛酸-6,3-内酯 | D-(+)-葡萄糖醛酸-3,6-内酯 | ||
| English alias | GLUCUROLACTONE | Tosylchloramide sodium | 00CE759F-D1F9-492E-89F7-B7400A34C72D | D-glucofuranuronate gamma-lactone | GLUCUROLACTONE [WHO-DD] | Glucuronolattone | D-Glucurono-6,3-lactone | Glucurolactonum | AKOS006341990 | BRN 0083595 | D70547 | Glucuronol | ||
| CAS number | 32449-92-6 | molecular formula | C6H8O6 |
| molecular weight | 176.12 g/mol | Exact mass | ≥99% |
| PSA | 104.000 Ų | logp | -1.800 |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram:
GHS07
Signal word:
Warning
Hazard Statement:
H302: 吞食有害
Statement of Preventive Measures:
P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P270: 使用本产品时,请勿进食、饮水或吸烟。 P330: 漱口 P301+P317: 如果被吞咽:请寻求医疗帮助。
WGK Germany:
2
Personal protective equipment:
Eyeshields,Gloves,type N95 (US),type P1 (EN143) respirator filter
RTECS:
LZ8930000
Production methods and uses
No production method and use information yet
Related
upstream information
No upstream information yet
downstream information
No downstream information yet
MSDS
Found 1 shareMSDS
3 2449-92 - 6 | D-glucuronolacton.pdf





