Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is a rhodium complex employed for preparing cationic COD-Rh complexes with phosphine ligands, e.g. for enantioselective hydrogenation (1), (2), (3) and hydrosilylation. (4) Rhodium complex employed for preparing cationic COD-Rh complexes with phosphine ligands, e.g. for enantioselective hydrogenation; Hydrosilylation Product class M-C, Homogeneous Catalysts, Diene/Dienyl Ligands Reaction type Hydrogenation, Asymmetric Reactions, C-H Activation, Hydroformylation, Asymmetric Hydrogenation, Hydrosilylation, Isomerization Chemical properties Chemical formula C 1 6 H 2 4 BF 4 Rh Empirical formula [Rh(cod) 2 ]BF 4 Molecular weight 406.07 Metal Rh Theoretical metal content 25 Physical state powder Color Metal purity brownish red 99.95
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Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Dangerous GoodsCAS number：35138-22-8 molecular formula：C16H24BF4Rh
overview
compound introduction
Specs
| Chinese alias | Chiralyst P407 | 四氟硼酸铑(I) 1,5-环辛二烯络合物 | ||
| English alias | Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate | 35138-22-8 | [rh(cod)2]bf4 | Bis(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate | MFCD00075045 | LYXHWHHENVLYCN-QMDOQEJBSA-N | (1Z,5Z)-cycloocta-1,5-diene; rhodium; tetrafluoroborate | (1Z,5Z)-cyclooct | ||
| CAS number | 35138-22-8 | molecular formula | C16H24BF4Rh |
| molecular weight | 406.07 g/mol | Exact mass | ≥99.95% metals basis |
| PSA | 0.000 Ų | logp | - |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram：
GHS05 , GHS02
Signal word：
Danger
Hazard Statement：
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H302: 吞食有害 H317: 可能引起皮肤过敏反应 H228: 易燃固体
Statement of Preventive Measures：
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P210: 远离热源，热表面，火花，明火和其他点火源。 - 禁止抽烟。 P302+P352: 如皮肤沾染：用水充分清洗。 P321: 特殊处理（请参阅此标签上的...）。 P405: 密闭存放 P501: 将内容物/
WGK Germany：
2
Personal protective equipment：
Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
UN Number：
2921
Packing Group：
II
Production methods and uses
No production method and use information yet
Related
upstream information
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downstream information
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MSDS
Found 1 shareMSDS
35138-22-8 | Bis(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate.pdf
