不溶于醚,微溶于冰醋酸、乙酸乙酯,在潮湿的空气中易潮解。 (1R)-(-)-10-樟脑磺酸是一种用于紫外/可见检测的高效液相色谱衍生试剂。它主要用于基底的解析。 (1R)-(-)-10-樟脑磺酸可作为手性构件用于通过对映选择性碳芳基化合成五价有机铋衍生物。基于光学活性聚苯胺膜的电位传感器可以将它作为手性单体用于手性氨基酸的对映选择性传感。 应用 (1R)-(−)-10-樟脑磺酸可作为合成砌块,用于通过对映选择性C-芳基化反应合成5价有机铋衍生物。 它可作为手性单体,用于基于光学活性聚苯胺薄膜的电位传感器介导的手性氨基酸的对映选择性感应。 Insoluble in ether, slightly soluble in glacial acetic acid and ethyl acetate, and easily deliquescent in humid air. (1R)-(−)-10-Camphorsulfonic acid is an HPLC derivatization reagent for UV/Vis detection. It is mainly employed for the resolution of bases. (1R)-(−)-10-Camphorsulfonic acid may be used as a chiral building block for the synthesis of pentavalent organo-bismuth derivatives by enantioselective C-arylation. It may be used as a chiral monomer in the enantioselective sensing of chiral amino acids by potentiometric sensors based on optical active polyaniline films.
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(1R)-(-)-10-Camphorsulfonic acid
Dangerous GoodsCAS number:35963-20-3 molecular formula:C10H16O4S
overview
compound introduction
Specs
| Chinese alias | (-)-樟脑-10-磺酸, (1R)-(-)-樟脑-10-磺酸, (1R)-樟脑-10-磺酸 | (-)-10-樟脑磺酸 | 樟脑磺酸 | ||
| English alias | ((1R,4S)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonic acid | Camphorsulfonic acid, (-)- | (-)-camphorsulfonic acid | L(-)-Camphorsulfonic acid | (-)-10-Camphorsulfonic Acid | (1R)-(-)-Camphor-10-sulfonic acid | (1R)-(-)-10-Camphorsulfonic | ||
| CAS number | 35963-20-3 | molecular formula | C10H16O4S |
| molecular weight | 232.3 g/mol | Exact mass | - |
| PSA | 79.800 Ų | logp | 0.5 |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram:
GHS05
Signal word:
Danger
Hazard Statement:
H314: 造成严重的皮肤灼伤和眼睛损伤 H318: 造成严重的眼睛损伤
Statement of Preventive Measures:
P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P301+P330+P331: 如误吞咽:漱口。不要诱导呕吐。 P304+P340: 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。 P363: 再次使用之前,请清洗受污染的衣物。 P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。 P
WGK Germany:
3
Personal protective equipment:
Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
UN Number:
3261
Production methods and uses
No production method and use information yet
Related
upstream information
No upstream information yet
downstream information
No downstream information yet
MSDS
Found 1 shareMSDS
35963-20-3 | (1R)-(−)-10-Camphorsulfonic acid.pdf





