The kinetic resolution of racemic 2-phenylbutyryl chloride by sterically hindered chiral secondary alcohols has been evaluated. 2-Phenylbutyryl chloride reacts with 4-methoxybenzoyl chloride catalyzed by PdBr(Ph)(PPh3)2 to yield 1-(4-methoxyphenyl)-2-phenyl-2-buten-1-one The kinetic resolution of racemic 2-phenylbutyryl chloride by sterically hindered chiral secondary alcohols has been evaluated. 2-Phenylbutyryl chloride reacts with 4-methoxybenzoyl chloride catalyzed by PdBr(Ph)(PPh3)2 to yield 1-(4-methoxyphenyl)-2-phenyl-2-buten-1-one
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2-Phenylbutyryl chloride
Dangerous GoodsCAS number:36854-57-6 molecular formula:C10H11ClO
overview
compound introduction
Specs
| Chinese alias | - | ||
| English alias | N-Boc-4-amino-3-fluoro-benzeneboronic acid pinacol ester | .alpha.-Phenylbutyryl chloride | 2-phenylbutanoyl chloride | InChI=1/C10H11ClO/c1-2-9(10(11)12)8-6-4-3-5-7-8/h3-7,9H,2H2,1H3 | MFCD20270360 | 2-Phenylbutyryl chloride, 98% | alpha-Ethylbenzeneacet | ||
| CAS number | 36854-57-6 | molecular formula | C10H11ClO |
| molecular weight | 182.65 g/mol | Exact mass | ≥98% |
| PSA | 17.100 Ų | logp | 3.300 |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram:
GHS05
Signal word:
Danger
Hazard Statement:
H314: 造成严重的皮肤灼伤和眼睛损伤
Statement of Preventive Measures:
P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P301+P330+P331: 如误吞咽:漱口。不要诱导呕吐。 P304+P340: 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。 P363: 再次使用之前,请清洗受污染的衣物。 P305+P354+P338: 如果进入眼睛:立即用水冲洗几分钟
WGK Germany:
3
Personal protective equipment:
Faceshields,full-face respirator (US),Gloves,Goggles,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter
UN Number:
3265
Production methods and uses
No production method and use information yet
Related
upstream information
No upstream information yet
downstream information
No downstream information yet
MSDS
Found 1 shareMSDS
36854-57-6 | 2-Phenylbutyryl chloride.pdf





