烯丙基硼酸季戊醇酯在简单酮亚胺的催化烯丙基化反应中被用作亲核试剂。 用途 作为试剂用于以下反应 钯催化的铃木宫村交叉偶联反应和烯烃复分解 分子间自由基加成 手性螺二茚二醇（SPINOL）基磷酸催化醛烯丙基化 钴催化二烯与烯烃的区域选择性加氢乙烯基化 核酸模板能量转移导致光释放反应 立体选择性铟催化的Hosomi-Sakurai反应 试剂用于制备 环砜羟乙胺作为BACE1抑制剂减少淀粉样蛋白β-肽 碳烯碘化钌与银羧酸盐的金属转移，得到碳氢活化的钌碳烯配合物作为Z选择性烯烃复分解的催化剂 烯丙基硼化试剂，用于制备烯丙醇[和高烯丙基胺 Allylboronic acid pinacol ester is used as a nucleophile in the catalytic allylation of simple ketoimines. Purpose Reagent used for Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis Intermolecular radical additions Allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids Cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes Nucleic acid-templated energy transfer leading to a photorelease reaction Stereoselective indium-catalyzed Hosomi-Sakurai reactions Reagent used in Preparation of Cyclic sulfone hydroxyethylamines as BACE1 inhibitors for reduction of Amyloid β-Peptides Transmetalation of carbene Ru iodide with Ag carboxylates to give C-H-activated Ru carbene complexes as catalysts for Z-selective olefin metathesis Allylboronation reagent for the preparation of allylic alcohols[10], and homoallylic amines
All
Chemical Reagents
Biomedicine
Organic raw materials
Inorganic chemical industry
intermediate
Agricultural chemicals
Auxiliaries and catalysts
Fragrances and Flavors
Dyes and Pigments
Daily chemical industry
Allylboronic acid pinacol ester
Dangerous GoodsCAS number：72824-04-5 molecular formula：C9H17BO2
overview
compound introduction
Specs
| Chinese alias | 丙烯基硼酸频哪醇酯 | 丙基硼酸频哪醇酯 | 烯丙基硼酸频哪醇酯 | 2-烯丙基-4,4,5,5-四甲基-1,3,2-二氧环戊硼烷 | 丙烯基硼酸邻二叔醇酯 | 2-烯丙基-4,4,5,5-四甲基-1,3,2-二氧杂环戊硼烷 | ||
| English alias | 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane | Allylboronic acid pinacol ester | Allylboronic acid, pinacol cyclic ester | allyl boronic acid pinacol ester | 4,4,5,5-tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane | ALLYLBORONIC ACID PIRACOL ESTER | ||
| CAS number | 72824-04-5 | molecular formula | C9H17BO2 |
| molecular weight | 168.04 g/mol | Exact mass | ≥96%(GC) |
| PSA | 18.500 Ų | logp | - |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram：
GHS07 , GHS02
Signal word：
Warning
Hazard Statement：
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H226: 易燃液体和蒸气
Statement of Preventive Measures：
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P210: 远离热源，热表面，火花，明火和其他点火源。 - 禁止抽烟。 P302+P352: 如皮肤沾染：用水充分清洗。 P321: 特殊处理（请参阅此标签上的...）。 P405: 密闭存放 P501: 将内容物/
WGK Germany：
3
Personal protective equipment：
Eyeshields， Faceshields， full-face respirator (US)， Gloves， multi-purpose combination respirator cartridge (US)， type ABEK (EN14387) respirator filter
UN Number：
1993
Packing Group：
III
Production methods and uses
No production method and use information yet
Related
upstream information
No upstream information yet
downstream information
No downstream information yet
MSDS
Found 1 shareMSDS
72824-04-5 | Allylboronic acid pinacol ester.pdf
