Bis(pinacolato)diboron is used to construct a tetramethylpyrrolidine nitroxide scaffold for the synthesis of paramagnetic heterocycles by Suzuki coupling. It is also a substrate used in new palladium-catalyzed cyclization of 1,6-enynes leading to homoallylic alkylboronates.用于乙炔和石蜡(铂催化)的顺式-连位硼化试剂; 钯催化的芳香族化合物的硼化。 钯催化的1,6-烯炔的环化生成高烯烷基硼酸盐(homoallylic alkylboronates)反应中的底物。 Bis(pinacolato)diboron is used to construct a tetramethylpyrrolidine nitroxide scaffold for the synthesis of paramagnetic heterocycles by Suzuki coupling. It is also a substrate used in new palladium-catalyzed cyclization of 1,6-enynes leading to homoallylic alkylboronates. A reagent used for the cis-vicinal diborylation of acetylenes and olefins with Pt catalysis; borylation of aromatics by Pd catalysis
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Bis(pinacolato)diboron
Dangerous GoodsCAS number:73183-34-3 molecular formula:C12H24B2O4
overview
compound introduction
Specs
| Chinese alias | 双戊酰二硼 | 双联频哪醇硼酸酯 | 4,4,4',4',5,5,5',5'-八甲基-2,2-联-1,3,2-二氧杂环戊硼烷 | ||
| English alias | 4,4,5,5,4',4',5',5'-octamethyl-[2,2']bi[1,3,2]dioxaborolanyl | bis (pinacolato) diborane | Dipinacoldiboron | dipinacol-diboron | MFCD00799570 | UNII-I906W26P4U | B2Pin2 | Bis(2,2,3,3-tetramethyl-2,3-butanedionato)diboron | bis(pinacolate)diborane(4) | DT | ||
| CAS number | 73183-34-3 | molecular formula | C12H24B2O4 |
| molecular weight | 253.94 g/mol | Exact mass | ≥98% |
| PSA | 36.900 Ų | logp | - |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram:
GHS08 , GHS05 , GHS07
Signal word:
Danger
Hazard Statement:
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H341: 怀疑引起遗传缺陷 H314: 造成严重的皮肤灼伤和眼睛损伤 H302: 吞食有害 H317: 可能引起皮肤过敏反应 H332: 吸入有害
Statement of Preventive Measures:
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染:用水充分清洗。 P321: 特殊处理(请参阅此标签上的...)。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P281: 根据需要使用个人
WGK Germany:
3
Personal protective equipment:
Eyeshields,Gloves,type N95 (US),type P1 (EN143) respirator filter
Production methods and uses
No production method and use information yet
Related
upstream information
No upstream information yet
downstream information
No downstream information yet
MSDS
Found 1 shareMSDS
73183-34-3 | Bis(pinacolato)diboron.pdf





