（R）-（+）-2,2′-双（二苯基膦基）-1,1′-双萘是用于不对称反应的轴向不对称双（三芳基）膦配体。 产品应用： 过渡金属催化的不对称反应（包括氢化和二甲硅烷基化）的有用配体。2,2′-双（二苯基膦基）-1,1′-联萘基及其铑和钌衍生物是还原芳基酮、β-酮酸酯和 α-氨基酮的高选择性均相催化剂。它们也已用于烯烃的不对称氢化和加氢甲酰化，不对称 Heck 反应和烯丙基的不对称异构化。 与 Ag（I）的络合物可用于催化烯基三氯乙酸酯和醛之间的不对称羟醛反应。也可与 Ag（I）一起催化偶氮化合物的对映选择性杂 Diels-Alder 反应。 (R)-(+)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene is an axially dissymmetric bis(triaryl)phosphine ligand for asymmetric reactions. Application Useful ligand for transition metal catalyzed asymmetric reactions, including hydrogenation and disilylation. 2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl and its rhodium and ruthenium derivatives are highly selective homogeneous catalysts used for the reduction of aryl ketones, β-keto esters, and α-amino ketones. They have also been used for asymmetric hydrogenation and hydroformylation of olefins, asymmetric Heck reactions, and asymmetric isomerizations of allyls. Complex with Ag(I) used to catalyze an asymmetric aldol reaction between alkenyl trichloroacetates and aldehydes. Also used with Ag(I) to catalyze an enantioselective hetero-Diels-Alder reaction of azo compounds.
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(R)-(+)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene
Dangerous GoodsCAS number：76189-55-4 molecular formula：C44H32P2
overview
compound introduction
Specs
| Chinese alias | (R)-(+)-BINAP | (R)-(+)-2,2'-联(二苯基膦基)-1,1'-联萘 | (R)-(+)-2,2′-双(二苯基膦)-1,1′-联萘 | (R)-(+)-BINAP, (R)-(+)-(1,1′-联萘-2,2′-二基)双(二苯膦) | ||
| English alias | (R)-(+)-BINAP | (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl | ||
| CAS number | 76189-55-4 | molecular formula | C44H32P2 |
| molecular weight | 622.67 g/mol | Exact mass | ≥93% |
| PSA | 0.000 Ų | logp | 11.400 |
numbering system
No numbering system information yet
physicochemical properties
No physical and chemical property information yet
Safety information
pictogram：
GHS07
Signal word：
Warning
Hazard Statement：
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H413: 可能对水生生物造成长期的有害影响
Statement of Preventive Measures：
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P273: 避免释放到环境中。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染：用水充分清洗。 P321: 特殊处理（请参阅此标签上的...）。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P304
WGK Germany：
3
Personal protective equipment：
Eyeshields,Gloves,type N95 (US),type P1 (EN143) respirator filter
Production methods and uses
No production method and use information yet
Related
upstream information
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downstream information
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MSDS
Found 1 shareMSDS
76189-55-4 | (R)-(+)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene.pdf
